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While vibrational spectroscopy is a well-known method of determining the structures of stable compounds, new techniques open up new possibilities of also analyzing unstable species In analogy to O=C=O, which is discussed in Section 42222, the isoelectronic unstable species HN=C=NH was studied by FTIR methods The two CN stretching vibrations are similar to those of' C02: vo,(CN) = 210470 cm '; u,(CN) = 1285 cm (Birk and Winnewisser, 1986) An unstable carbon oxide, the linear species O=C=C=C=C=C=O, was also investigated in the gas-phase (Holland et al, 1988) and as a matrix isolated species (Maier et al, 1988) Comparable to CO2 is the molecule CSe2 It was investigated by high-resolution FTIR spectroscopy because precise structural determination of free molecules by microwave spectroscopy are limited to molecules which have a permanent dipole moment.



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Hence, other molecules have to be investigated by electron diffraction or high-resolution infrared techniques Two recently studied examples are the Dmh species CSel and HF; The following molecular constants with the standard error in parentheses of CS0Se2 were measured: vl = 3691331(12) cm-' (obtained from a combination band), u = 3130539(10) 2 cm-I, v3 = 13018774(5) cm From the rotational fine structure the equilibrium bond length r-,(CXOSe)= 16935536( 19) pm was determined (Burger and Willner 1988) Spectra of the linear anion FHF in the gas phase were obtained by diode laser spectroscopy: L / I = 5836539(13) cm u = 12860284(22) cm-', and u = 13311502(7) 2 cm From the resulting rotational constants an equilibrium F-F internuclear distance of 227771(7) pm was calculated (Kawaguchi and Hirota, 1987) In the class of binary hydrides, boron compounds are especially interesting.





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ImportError. This error is generated when an attempt is made to import a module that does not exist or the interpreter is unable to locate it. This error can also occur when the from-import statement is not able to import a name that is requested. Following is the example of when the import statement fails.

A recent FTIR investigation revealed the out-of-plane vibration of unstable BH1: 11408757(39) cm-' (Kawaguchi et al, 1987) These data confirm the results of a recent matrix study which showed an absorption at 1132 c n - ' for the same vibration (Kaldor and Porter, 1971) A detailed.

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9.15.3.2 PDF of S The PDFs of the largest eigenvalues of S in all the cases above can be found by taking the derivative of the CDF with respect to x. A compact form of these PDFs may be obtained by using the following classical formula on the derivative of determinants [236, Eq. (9)] d d detA(t) = detA(t)tr A 1 (t) A(t) dt dt (9.764)

Illustration of hold-up (left) and product (right), experiment V-15.

In Practice (continued)

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Recently, the changeover is being made from the analogue to the digital baseband signal for SNG transmission, due to the improvement of digital video compression techniques which makes the transmission system smaller and lighter. Digital SNG also has the following characteristics: 1) better portability of transmission equipment; 2) effective use of the transponder; 3) lower cost; 4) lower transmission e.i.r.p.; 5) lower power consumption; 6) less interference between channels; 7) scrambling of the transmission signal. Digital SNG services with these characteristics will wholly replace the analogue ones. The video coding method is already recommended in ITU-T Recommendation J.81 (34 ~ 45 Mbps) for long-distance circuits. The most recent video coding method, based on ITU-T Recommendation H.262 (MPEG-2), although not yet recommended, will probably be recommended for digital SNG services in the future. Analogue and digital baseband signals are indicated as follows.

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