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The detection and measurement of dimethylnitrosamine by laser Raman spectroscopy has been reported by Thomas (1977). This compound is carcinogenic. Raman spectroscopy was chosen for several reasons: 0 the compound is highly water soluble, and Raman scattering caused by water is quite weak, 0 there are two intense Raman active vibrational modes which can be used for quantification, 0 with high power lasers it is possible to study highly diluted samples. The lowest concentration which could be detected by the authors was 10 mg L-'. Application of laser Raman multichannel spectroscopy to a kinetic investigation in the liquid phase has been reported by Crunelle-Cras and Merlin (1977). A multichannel spectrometer with photoelectric image devices, interfaced with a data aquisition and handling system, permits the study of fast processes, exemplified by the fast oxidation of the sulfite ion by the bromate ion in an acidic medium. The use of laser Raman spectrometry in order to quantitatively investigate the urea synthesis under process conditions has been reported by Van Eck et al. (1983). Only Raman spectroscopy seems to suit the problem, since the visible radiation which is used to excite and detect Raman transitions can easily be directed to a measuring cell. Furthermore, water, which is an acceptable solvent, and all compounds involved in the synthesis show characteristic Raman bands. In order to compensate for many of the instrumental factors relative intensities were used instead of absolute intensities. Reproducible window mountings are a necessity. The effect of pressure and temperature on the Raman intensity have to be taken into account if measurements are to be carried out in situ (Sec. 6.8). The effect of the temperature is moderated by using an internal standard.



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where ju is the standard state chemical potential, a function only of temperature. The activity ai of species / is defined by

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The main RED control parameters are illustrated in Table 32 In RED, the probability of early drop packet discarding depends on various parameters The packet drop probability calculation follows [2]: Pb = Pmax (avg Qmin)/(Qmax Qmin) Pa = Pb / (1 count * Pb) Where: Pb = initial drop probability Pa = actual drop probability avg = weighted-average queue length Pmax = maximum drop probability count = number of enqueued packets since the last dropped packet It follows that initial probability varies from 0 (zero) to Pmax, and the actual drop probability increases with the number of enqueued packets since the last one was dropped The general effect is that higher rate flows will have a higher number of dropped packets, since their packets arrive at a higher rate than slower rate flows.

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A symmetry operator causes a symmetry operation. It moves a molecule into a new orientation, equivalent to its original one. Symmetry operations may be represented by algebraic equations. The position of a point (an atom of a molecule) in a Cartesian coordinate system is described by the vector r with the components x, y , z. A symmetry operation produces a new vector r/ with the components x', y', z. The algebraic expression representing a symmetry operation is a ' matrix. A symmetry operation is represented by matrix multiplication. A general rotation of a Cartesian coordinate system is described by:

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