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where 1 K (Lc , L) = 2

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Column C contains the multipliers for each digit: alternating 2s and 1s. Column D contains formulas that multiply the digit in column B by the multiplier in column C. For example, the formula in cell D5 is:





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Camp, D. C. and L. M. Langer. Phys. Rev. 129, 1782 (1963). Meyerhof, W. E. Elements of Nuclear Physics, McGraw-Hill, New York, 1967. Moszkowski, S. A. Phys. Rev. 82, 35 (1951). Wu C. S. et al. Phys. Rev. 105, 1413 (1957).

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PSPS of reactive membrane separation with diagonal [ ]-matrix For the ideal ternary system discussed in Section 4.4.2.1, the PSPS is the same as for the reactive distillation example in Section 4.2.3.1 (see Fig. 4.4(b)) if one changes the vertices. It is worth mentioning, that the reactive reboiler is just a special case of the reactive membrane separation process with a scalar [k]. Now, the question arises how the PSPS and the branch of stable singular points will be influenced by a membrane having a diagonal mass transfer matrix. In Fig. 4.31 the PSPS are presented for different CC-values. The solid lines represent the different branches of stable nodes. Clearly, there exists a critical value, CC,crit = 5/3, above which the PSPS is turned from the C-vertex towards the B-vertex. At the intersections of the PSPS with ), reactive arheotropes are located. They the chemical equilibrium surface (Da move towards the B-vertex with increasing C-selectivity of the membrane that is, increasing CC-value. Above a certain value, the reactive arheotrope coincides with the pure B-vertex and at this point the PSPS is tangential to the chemical equilibrium surface. Generalization For a more generalized analysis of the qualitative influence of membranes on the singular points, the reactive membrane separation process is now considered with a nondiagonal [ ]-matrix. The condition for a kinetic arheotropes is given by

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FIGURE 11.15. Bar diagrams representing deuterium levels of an + fragment ions derived from a model peptide Ac-GWW(LA)8 LWWA-Etn (left) and Ac-GWW(LA)4 P(AL)4 WWAEtn (right) using collision-induced dissociation of Na+ -cationized molecular ions of the peptides that were incorporated in DMPC bilayers and incubated in deuterated buffers for the time periods indicated on the graphs. Models for the incorporation of the peptides in a bilayer are presented on the insets. Fast-exchanging segments of the peptides are indicated in gray. Adapted with permission from (107).

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