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void bomb(char *message); int main(void) { WINDOW *p,*s1,*s2,*s3; FILE *f; int ch; initscr(); /* create a new pad */ p = newpad(200,WIDE+1); if( p == NULL ) bomb( Unable to create new pad\n ); /* create three subpads */ s1 = subpad(p,TALL,WIDE+1,0,0); if( s1 == NULL) bomb( Unable to create subpad 1\n ); s2 = subpad(p,TALL,WIDE+1,TALL,0); if( s2 == NULL) bomb( Unable to create subpad 2\n ); s3 = subpad(p,TALL,WIDE+1,2*TALL,0); if( s3 == NULL) bomb( Unable to create subpad 3\n ); /* open the file */ f = fopen(FILENAME, r ); if( f == NULL) bomb( Unable to open file\n ); /* display file s contents on the pad */ while( (ch=fgetc(f)) != EOF) waddch(p,ch); fclose(f); /* display the pad s contents on the screen */ prefresh(s1, 0, 0, 0, 0, TALL-1, WIDE); prefresh(s2, 0, 0, 0, WIDE+SPACER, TALL-1, WIDE*2+SPACER); prefresh(s3, 0, 0, 0, WIDE*2+SPACER*2, TALL-1, WIDE*3+SPACER*2); wgetch(p);



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Block "B"

11

Figure 12.1. Microphase separation in bulk lms of azo diblock copolymers with well-de ned structures. The light domains represent the azo segment A, whereas the dark parts are formed from another non-azo block B.

Listing 11-4 (continued)

ACT pattern is used to let clients identify different results of asynchronous invocations when the reply has arrived.

47 48 49 50 51 52 53 54 55 56 57 58 endwin(); return 0; } void bomb(char *message) { addstr(message); refresh(); getch(); endwin(); exit(1); }





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cylinders), lamellae, or continuous phases by gradually increasing the azo content in the BC composition, which makes their properties different from those of azo polymer blends or azo random copolymers. Figure 12.1 shows a schematic representation of the microphase separation of an AB-type diblock copolymer, in which block A is an azo polymer segment and block B represents a non-azo polymer. Even if the azo block constituent is the minority phase in BC lms on the nanoscale (o100 nm), it retains its photochemical sensitivity and can be photomanipulated into an ordered state with the transition moments of azo moieties almost perpendicular to the polarization direction of the actinic light according to the Weigert effect (e.g., Ikeda, 2003a), which improves its optical performance by eliminating the scattering of visible light. Azo groups in the majority phase show a behavior similar to that of azo homopolymers. Additional performances such as hydrophilicity (e.g., Yu et al., 2006a,b), crystallization, optical transparency (e.g., Yu et al., 2007a,b), thermoplasticity (Cui et al., 2004), ionization (Qi et al., 2005), and water solubility (Ravi et al., 2005) can be acquired by special molecular design of the non-azo block B. Since the fascinating azo BC offers an effective and convenient method to design advanced materials with more than two functionalities, it has become one of the emerging topics in novel azo materials. This chapter tries to introduce this eld from the preparation method and basic properties to the control of their

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The program s output is identical to the original, but some effort was saved by using local references to the subpads in lines 43, 44, and 45.

instantiates AsyncRequestor void invoke() void invokeFireAndForget() ... ClientInvocationHandler String endpointURL String operationName Object[] arguments QName returnType Call constructCall() ...

Here s a bit of advanced NCurses for you: The code in the previous section uses three prefresh() functions in PADDY2.C to update pad data to the standard screen:

supramolecular self-assembly and the microphase separation in bulk lms of azo BCs, as well as their applications.

prefresh(s1, 0, 0, 0, 0, TALL-1, WIDE); prefresh(s2, 0, 0, 0, WIDE+SPACER, TALL-1, WIDE*2+SPACER); prefresh(s3, 0, 0, 0, WIDE*2+SPACER*2, TALL-1, WIDE*3+SPACER*2);

These three statements work, but they re inefficient. Each prefresh() internally calls two lower-level NCurses functions: pnoutrefresh() and doupdate(). The pnoutfresh() function examines a given rectangle of text in a pad, and notes that the text in that rectangle that has been changed or updated since the last prefresh(). That text, referred to as touched, is then queued up for display on the standard screen. Then the doupdate() function takes care of the task of actually updating the screen. So the three prefresh() functions actually work out to be:

SyncInvocationHandler Object invoke() ...

To obtain regularly ordered nanostructures of microphase separation in BC lms, BCs should have well-de ned structures, narrow molecular weight polydispersities, and each block has to be larger than a certain minimum molecular weight. Several polymerization methods, such as anionic, cationic, free-radical, and metalcatalyzed polymerizations, have been explored to build BCs that meet these requirements. Owing to the existence of azo groups (Ph N=N Ph) with a long conjugation of p electrons, not all the living polymerization techniques are appropriate for synthesizing azo BCs with a suitable molecular weight. Therefore, several modi ed ways have been developed.

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