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Figure 12.20. Enhancement of surface index modulation of azo BCs by cooperative effect. A is aligned, and R is random. Source: Reproduced from Yu et al., 2008a.

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Figure 14-1: The help window is boxed Main window 0,0



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over a large area on soft or hard substrates (PET sheets, Si wafers, and quartz plates) via the selective Ag+ doping of the hydrophilic PEO domains in a microphase-separated azo LCBC lm and an associated vacuum ultraviolet UV (VUV) treatment to eliminate the LCBC templates to reduce simultaneously the Ag+. Obviously, the periodicity of the highly dense Ag nanoparticles was precisely controlled by the nanotemplates of the azo LCBC lms. The simple and facile fabrication of a metal nanoparticle array can be used as a novel type of BC photolithography to overcome the size limitations of conventional top down lithography, with the goal of macroscopically fabricating hierarchical nanopatterns with controlled ordering for potential applications ranging from photonics and plasmonics to metal wiring in molecular electronics (Suzuki et al., 2007). The self-assembly from azo LCBC lm templates also provides a good method to modify the nanoscale shape of various kinds of functional materials, such as electric conducting RuO2, magnetic Fe, or organic conducting polymers (Suzuki et al., 2007).





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24.09.2004 21:09

Substrate Microphase-separated nanotemplate d D Substrate Ag nanoparticles VUV reduction VUV etching

main window main = newwin(0,0,maxy,maxx) subwindow sub = subwin(main,maxy-2,maxx-2,1,1)

Subwindow inside main window (Write stuff to this window) Figure 14-2: Protecting a box from being overwritten

Figure 12.21. Fabrication of periodic array of Ag nanoparticles on either exible or rigid substrates. The gray closed circles represent the photoreduced metallic Ag nanoparticles with regular particle size and periodicity. Source: Reproduced with modi cations from Li et al., 2007b.

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Figure 12.10 presents a PEO-based azo LCBC lm, which exhibits wellordered hydrophilic PEO nanocylinders with hexagonal packing embedded in an azo LC matrix. The anisotropic PEO nanocylinders can be used as ion-conductive channels since PEO has been widely used as a solid electrolyte (Fig. 12.22). By incorporating LiCF3SO3 into the PEO nanocylinders, a supramolecular complexed structure and anisotropic ion transportation were achieved on the basis of the azo LCBC nanotemplate (Li et al., 2007a). Highly ordered ion-conducting PEO nanocylinder arrays with perpendicular orientation were formed by coordination between the lithium cations and the ether oxygens of the PEO blocks. At low- and medium salt concentration, selective complexation of Li+ with the PEO phase leads to the formation of an ordered array of ion-conducting PEO nanocylinders, which are perpendicular to the substrate surface, and on the right-hand side of Fig. 12.22, there is a 3-D illustration of the corresponding phase-segregated structure, in which anisotropic ion transport is observed. At high salt concentration, the lithium salt is dissolved in both PEO and azo domains. This decreases LC ordering and disturbs microphase separation. An array of tilted and distorted nanocylinders is formed with poor regularity. Consequently, the anisotropic value of ion conductivity is reduced (Breiner, 2007). On the surface of PEO-based azo LCBC lms, each hydrophilic PEO domain appears as a circular hollow surrounded by the hydrophobic azo matrix. These amphiphilic properties enable the selective absorption of Au nanoparticles with hydrophilic or hydrophobic surface modi cations. Of course, the surface properties of the gold nanoparticles are a critical factor in this nanofabrication (Watanabe et al., 2007). To extend site coverage further and favor high selectivity,

N OT E Here s a tip: If the window is small and the box takes up too much space, consider merely coloring the window instead. Use bkgd() as described in 3.

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