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The feasibility of using the trans cis photoisomerization of azobenzene to trigger the reversible dissociation and formation of BCP micelles is now demonstrated. Research on this topic certainly will continue, owing to the great interest from both fundamental and applied points of view. Fundamentally, many exciting and intriguing issues remain to be studied. For instance, what is the substitution pattern on azobenzene that will give rise to the largest increase in polarity upon trans cis isomerization For a given azobenzene polymer hydrophobic block, how to adjust the relative length of the hydrophilic block to make the hydrophilic hydrophobic balance most sensitive to the isomerization-induced change in polarity Among the azobenzene amphiphilic BCPs known to date, most, if not all, of the used hydrophobic polyacrylates or polymethacrylates are LC polymers bearing azobenzene mesogens. The question remains unanswered as to how the effect of the trans cis photoisomerization on the LC phases, which can be important due to the photochemical phase transition, could affect the thermodynamic and kinetic stability of polymer micelles. In terms of new designs, BCPs offer a great platform for exciting opportunities. Schematically presented in Fig. 6.12 is such an example. The idea in Fig. 6.12 is to prepare a light-responsive schizophrenic diblock (AB) copolymer micelle using azobenzene; that is, the core- and shell-forming blocks can be reversed upon illumination at two different wavelengths. Ames et al. rst



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This time the index line appears. The slk_restore() function is used primarily in conjunction with slk_clear(). The slk_clear() function removes the soft labels from the

trans-azo 1 trans-azo 2 (large dipole moment) (small dipole moment)

Your screen will probably show something different. The point is the same: You re in the NCURSES directory and ready to create some source code with your editor. Source code is presented in this book as follows: First comes the filename, then the source code. To the left are line numbers for reference purposes only. Do not type the line numbers! Use your editor to name (or create) the file; then input all the text exactly as shown in Listing 1-1.

Security in a service-oriented architecture with a potentially large number of participants requires a means to discover the security policies.





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1 2 3 4 5 6 7 8 9 10 #include <ncurses.h> int main(void) { initscr(); addstr(Goodbye, cruel C programming!); endwin(); return 0; }

cis-azo 1 (small dipole moment)

So if you re using vim, you would type:

supported by a partner without human intervention. XACML [Oas03b] allows developers to define access control policies. Web Services endpoints can be described with the mandatory features of service invocation, optional features that they support, and a preference order among those features. WS-Policy [BCH+03] provides a framework for defining the properties of Web Services as policy statements. Its security addendum WS-SecurityPolicy [DHH+02] can be used to describe the security properties of a Web Service.

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N OT E Note that some compilers require there to be an extra blank line following the last line of code. This is not shown above or in any sample code in this document.

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When you re done entering text, double-check to ensure that you didn t miss anything. Note that from now on it s assumed that whenever you see source code as shown here, you are to type it and name it according to the source code heading. And, naturally, you don t have to type every program, only those you want to experiment with.

There are many possible ways to realize LOOKUP with Web Services, and there are a number of proprietary implementations. UDDI [Oas02] is a standard for an automated directory service that allows the developer to register and look up services. In contrast to many simple naming and property services, UDDI started with the vision of providing a world-wide, replicated registry for business services, similar to the Domain Name Service (DNS) for Internet domain names. A central registry server, called the Universal Business Registry (UBR), is provided by a number of vendors, including Microsoft and IBM. All UDDI specifications use XML to define data structures. An UDDI registry includes four types of document that make up the simple basic data model of UDDI: A business entity is a UDDI record for a service provider A business service represents one or more deployed Web Services A technical model (tModel) can be associated with business entities or services A binding template binds the access point of a Web Service and its tModel UDDI allows a service provider to register information about itself and the services it provides, such as the service provider s name, contact information, and description. Arbitrary contact information can be registered, including URLs that refer to Web Services. Technical details of a Web Service are also registered, such as the protocol supported. The most common Web Services protocols, such as HTTP and SMTP, are pre-registered in UDDI registries as so-called tModels. tModels are

Figure 6.12. A possible design of light-responsive schizophrenic micelle based on azobenzene-containing diblock copolymers.

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