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Methanol Conversion to Hydrocarbons Methanol-to-gasoline (MTG) chemistryon zeolite H-ZSM-5 and the closely related process of methanol-to-olefin (MTO) chemistry also catalyzed by H-ZSM-5 attracted attention because it is one of the most successful routes for the conversion of methanol to synthetic fue1 638 It has also generated great interest in fundamental studies Two excellent reviews on catalytic materials 639 and process640 technology are available MTG/ MTO chemistry has been intensely studied, and new basic information is still acquired by using a wide variety of methods, both theoretical studies641 -644 and spectroscopic techniques 645 -647 It has been established that methanol is first dehydrated to dimethyl ether and an equilibrium mixture of these two compounds and water is formed.



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Restoring to an Earlier Time . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 82 Configuring System Restore . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 84





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A study using an in situ flow variable-temperature MAS NMR revealed, however, that there is no equilibrium between methanol and dimethyl ether at high temperature and that surface methoxy groups do not exist at high temperature 648 Methanol and dimethyl ether then converted to olefins, aliphatics, and aromatics up to C w It is also known that there is an induction period before the onset of extensive hydrocarbon synthesis The mechanism of these transformations, especially the formation of the first C-C bond and the nature of the intermediates involved, is still a matter of significant debate Further fundamental questions are how methanol or dimethyl ether is converted to alkenes, why propylene is formed with higher initial selectivity than other olefins, and how aromatics are produced Theoretical investigations indicated641 ,642 that two main pathways are possible for the first, dehydration step.

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that goal, and a d d r still being helpfully inclined to s p k r ) , and (ii)a d d r actually eventually does oc., or at least brings about a state where a d d r believes it is mutually believed that it wants the ideal situation. (Cohen and Levesque, 1990b, p. 241)

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One proceeds via a methoxy surface intermediate (10) formed as a result of the adsorption of methanol on acidic site of the zeolite (HO-Z) to give dimethyl ether [Eqs (363) and (364)] The other, direct route is a reaction between two methanol molecules adsorbed simultaneously on the same active site [Eqs (365) and (366)]:.

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image placed on the upper-left corner of the Property inspector is generally sized at 36 pixels square and placed 3 pixels from the top and 2 pixels from the left. Although you are not required to keep this size image or its placement following these guidelines helps make your custom Property inspectors resemble the standard Dreamweaver ones. a good idea to lay out your Property inspector with the View Visual Aids Invisible Elements option disabled. The small icons that indicate AP elements can alter the perceived spacing.

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