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The difference in initial slope is attributed to the different number of catalytic sites involved in the two reactions If water is stripped from the liquid, coverage of the catalyst surface with water molecules decreases, and in consequence both reactions are running faster However, the increase of ether formation is proportional to the square of the progress of the esterification, because of the square in the adsorption term in the ether rate expression (3) Therefore, stripping of water increases the rates, but lowers the selectivity at low conversion levels If the conversion level increases, the reactant concentrations decrease As the esterification is of first order in acid, but the etherification of second order in alcohol, the latter suffers more from low reactant concentrations In consequence, the instantaneous selectivity increases with increasing conversion levels The sharp drop at high conversion levels is caused by the equilibrium limitation of the esterification.



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A pipe lets you direct the output of one command to be the input of the next command, so in this example, the output of the ps command (a list of processes) is directed to the less command, which lets you page through that information. Use the spacebar to page through and type q to end the list. You can also use the arrow keys to move one line at a time through the output.

The HLOOKUP function s arguments are as follows:

If the equilibrium is reached, no more ester is formed, whereas the etherification continues As the equilibrium depends on the water concentration, the drop of Sinst to zero occurs at higher conversion levels, if water has been stripped from the liquid..

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double t = 0.0; if (f2*QL_EPSILON > 0.125 && fabs(x2-f2) < sqrt(QL_EPSILON)*f2) { t = exp((1 t)*(2 t/(f2+1)))/sqrt(2.0*pi_*(f2 + 1.0)); } else { t = exp(f2*log(x2) x2 GammaFunction().logValue(f2 + 1)); } double ans = v*t; bool ag = false; int n = 1; double f_2n = df_ + 2.0; f_x_2n += 2.0; double bound; for (;;) { if (f_x_2n > 0) { ag = true; goto L10; } for (;;) { u *= lam / n; v += u; t *= x / f_2n; ans += v*t; n++; f_2n += 2.0;

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A molecule with n atoms can be described by a Cartesian system whose origin is at the center of mass and whose axes correspond to the inertia axes. An atom i with mass m, performing a motion is characterized by its equilibrium coordinates aio(a = x, 4 z and ;) its general coordinates a;. Displacement from the equilibrium position is described by A(T;= (T, m,o. The column vector xi, ..., z is noted X , the corresponding row vector is , the transposed vector noted XT. The kinetic energy T of the molecule can be expressed by

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