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The reversible trans cis photoisomerization of azobenzene and its derivatives make polymers and liquid crystals (LCs) bearing this chromophore a suitable medium for recording a diffraction grating for light. Using photosensitive materials, a diffraction grating basically is a periodical change of refractive index, with the period being in the order of the wavelength of light to be diffracted. As schematically illustrated in Fig. 11.1, when a lm of an azobenzene-containing polymer or LC is exposed to a recording light going through a grating photomask, or without mask, to an interference pattern (high and low intensity) generated by two coherent recording laser beams, a grating structure or pattern can easily be formed because of the change in refractive index in the reactive regions hit by light. Various events in the reactive regions, which are all related to the photoisomerization of azobenzene, can give rise to the index change. First, the simple conversion of trans-azobenzene to cis-azobenzene can result in an index change, since the two isomers do not have the same index. In this case, the index modulation, which is the difference in refractive index between the reactive and nonreactive regions, is usually small. Second, the photoinduced orientation (alignment) of azobenzene moieties can change the refractive index. In this case, the recording light needs to be linearly polarized to induce orientation of azobenzene in the direction perpendicular to the polarization, through the mechanism of hole burning or angular selection (Ikeda, 2003; Natansohn and Rochon, 2002; Ichimura, 2000; Rasmussen



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public class ThisIsAnotherClass { public void TheResultIsHere( IAsyncResult res ) { RemoteAddCallDelegate racd = (RemoteAddCallDelegate) ((AsyncResult)res).AsyncDelegate; Console.WriteLine( "result: " + racd.EndInvoke(res) ); } }

N OT E It s possible to program NCurses in Windows when using the Cygwin environment. I ve not toyed with Cygwin, so I m unable to comment on it here. For more information, refer to www.cygwin.com.

Smart Light Responsive Materials. Edited by Yue Zhao and Tomiki Ikeda Copyright r 2009 John Wiley & Sons, Inc.

NCurses is about programming the terminal screen, so you ll need access to a terminal screen or window to run the programs. You can either use one of the virtual terminals (which you can access on most PCs by pressing Alt+F1, Alt+F2, Alt+F3, and so on) or open a terminal window in the X Window System environment or in Mac OS X using the Terminal program. (See Figure 1-1.)





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The compiler creates the EndInvoke operation in a way that returns the result of the target operation without a manual downcast. .NET also supports the Asynchronous Completion Token (ACT) pattern [SSRB00]. The last parameter to BeginInvoke, null in the example here, can be used to supply an arbitrary value (the ACT) that can be accessed from the callback method to identify the asynchronous request. Oneway operations Oneway operations are the .NET implementation of FIRE AND FORGET; that is, the .NET framework provides best-effort semantics. In other words, nobody knows whether the operation is actually executed. Oneway operations when used in the simplest way provide no feedback about the result of an invocation execution, be it a return value or an exception. This is the reason why oneway operations must have a void return type. To make an operation a oneway, the operation declaration needs to specify this. Oneway operations have to have the [OneWay] attribute. The following example shows this:

Note that the terminal you choose can affect what NCurses does. Not all terminal types can, for example, do color or draw lines on the screen.

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Figure 11.1. Schematic illustration of the possible periodic changes in refractive index related to the photoisomerization of azobenzene. Black strips designate irradiated areas.

1

The program you use in the terminal screen is a shell. It displays a shell prompt and lets you type one of the gazillions of UNIX commands and what not which is all basic UNIX stuff. The following sections review basic shell operations and a smattering of commands. If you feel you already know this, skim up to the section titled Make a Place for Your Stuff.

public interface ILogger { [OneWay()] void logMessage( string message ); void store(); }

et al., 1999; Pham et al., 1997). Third, with azobenzene LCs, the photochemically induced phase transition, generally nematic to isotropic, can also give rise to an index change (Yoneyama et al., 2002; Ikeda and Tsutsumi, 1995). Although azobenzene mesogens in the elongated trans form are compatible with ordered LC phases, the bent cis isomer is usually incompatible with them, and the perturbation effect may be enough to isothermally transform the LC phase into the isotropic state, or induce disorder in the LC phase. The diffraction ef ciency Z is an important parameter for a grating. In the case of transmission grating in the Raman Nath regime, it is related to the refractive index modulation Dn through ZE(pdDn/l)2, where d is the thickness and l the wavelength of the probe light (Yoneyama et al., 2002). The index modulation obviously is governed by the combination of a number of factors, including the used azobenzene materials, the grating formation mechanism involved, and the recording conditions. The rst-order diffraction angle Y is related to the grating period L (fringe spacing) through L = l/(2 sinY). It should be emphasized here that the grating schematized in Fig. 11.1 is a volume grating, that is, the index change occurs throughout the thickness direction of the lm. Upon exposure to an interference pattern with no mask, a remarkable property of azobenzene polymers is the formation of surface relief grating (SRG) as a result of a mass transport triggered by the trans cis photoisomerization (Kim et al., 1995; Rochon et al., 1995). As reviewed in s 4 and 8 there has been a

For example, the standard Bourne shell may look like this:

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