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Rating 5/10 This chapter summarizes several topics that are currently progressing in the research areas of photoresponsive monolayers and LC ultrathin polymer lms. The surface photoalignment method using command surface is now extending to a branch of organic inorganic nanohybrid systems. Thus, surfacemediated processes provide new opportunities to exert micropatterning of simple components to various composite systems. Such approaches would be of particular use in fabrication of optical devices. Surface-grafted LC photoresponsive polymer lm can be a new target of LC lm research. The orientation of the Az mesogenic group strongly in uences the photoresponse behavior and sensitivity. Since the planar-arranged Az mesogens should be more sensitive to LPL, fabrications of highly sensitive photorecording media may be realized. Furthermore, smart photoresponse functions such as photoswitchable anisotropic friction properties may be anticipated. In the LC molecular and polymer assembly systems, the light trigger is effectively converted into the molecular motions to induce orientation and migration in cooperative manners. Motions are basically driven by thermal selfassembly processes of the soft materials. Suggestive examples can be seen in the mass migration systems. In the LC PT type, the relief formation is most likely to be the consequence of the microscopic deformation of the lm occurring at the LC isotropic interface formed within the lm. This situation is in marked contrast to the migration mechanism in the conventional amorphous materials. As shown here, the detachment of Az chromophore (bleaching the color) will be a promising strategy to expand optical applications of the photogenerated relief structure. With respect to the alignment control, the marked research advance in the block copolymer systems is to be emphasized. Here, the photoalignment is not best pdf editing software reddit Free PDF Editor - Download
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