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In recent years, polymer brushes have become fascinating subjects in polymer research. They are de ned as dense layers of end-grafted polymer chains con ned to a solid surface or interface (Advincula et al., 2004). Recently, well-de ned polymer brush structures with a high graft density have been developed using living radical polymerization, such as the atomic transfer radical polymerization (ATRP) method (Tsujii et al., 2006; Edmondoson et al., 2004). Since the ATRP can be performed using various types of monomers, many functional polymer brushes can be designed. Introduction of LC properties into the surface-graft chains seems of great interest in view of fabrication of smart responsive surfaces (Hamelinck and Huck, 2005; Peng et al., 1999). Uekusa et al. (2007) have synthesized LC polymer brushes bearing an Az mesogenic group in the side group by adopting the surfaceinitiated ATRP method. The polymer brushes have characteristic properties quite different and unpredictable from those of the spincast lms. A unique orientation behavior of a smectic LC state in the thin lms prepared by the surface-initiated polymerization is indicated. UV-visible absorption spectroscopic measurements reveal that the Az mesogens adopt a parallel orientation in the lm, which is in sharp contrast to that in a spincast lm of the identical polymer. A normal orientation of the mesogenic groups is commonly observed for the spincast lms of smectic LC Az polymer (Han et al., 2000, 1999; Geue et al., 1997).



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int touchline(WINDOW *win, int start, int count);

invoke(...) send()

win is a WINDOW variable representing a window created earlier in this program, or stdscr for the standard screen. start is an int value representing the starting row to be updated. Values range from 0 for the top row on through as many rows as there are in the named window. count is an int value that tells NCurses how many rows to update. Values range from 1 for just the named row, on up to as many rows as there are from the current row to the end of the window.





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A 2-D XRD pro le of the grafted polymer lm recorded on an imaging plate is depicted in the top portion of Fig. 8.6. Diffraction patterns are observed only in the in-plane direction, that is, the periodic structures derived from the smectic LC phase are perpendicular to the substrate plane with LC mesogens being aligned parallel to the substrate. An in-plane orientation of mesogens is often observed in a microphase-separated state of LC block copolymers (Mao et al., 1997); however, to our knowledge, this type of smectic LC orientation in a polymer lm was observed for the rst time. In the one-dimensional (1-D) pattern, a clear peak is observed at 2y=2.481, which corresponds to a layer spacing of 3.56 nm. This spacing corresponds to a long-range ordering of approximately the length of the fully extended Az side chain, suggesting the formation of interdigitated structures of Az side groups. In contrast, a diffraction pattern on the spincast lm of the identical homopolymer is observed only in the out-of-plane direction at 2y=2.731 (d=3.26 nm) (Fig. 8.6, bottom). On the basis of the spectroscopic and X-ray data, schematic illustrations of the structure of the surface-grafted and spincast polymer lm are shown in Fig. 8.7.

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keypad(menu,TRUE);

X-ray beam (CuK )

Here, reading of special keys from the keyboard is possible by wgetch() functions reading input from the window menu.

write ()

1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 #include <ncurses.h> int main(void) { int ch; initscr(); keypad(stdscr,TRUE); do { ch = getch(); switch(ch) { case KEY_DOWN: addstr( Down\n ); break; case KEY_UP: addstr( Up\n ); break; case KEY_LEFT: addstr( Left\n );

X-ray beam (CuK )

23 24 25 26 27 28 29 30 31 32 33 34 break; case KEY_RIGHT: addstr( Right\n ); default: break; } refresh(); } while(ch != \n ); endwin(); return 0; }

The second alternative uses a separate thread within the server application, here illustrated inside the INVOKER. In this case, the invocation data sent over the network has to have a flag that instructs the INVOKER to execute the operation asynchronously. This flag is not shown in the diagrams. This allows a synchronous acknowledgement to be received,

Sample output:

Figure 8.6. Grazing-angle X-ray diffraction patterns for surface-grafted polymer (top) and spincast (bottom) thin lms of LC Az polymer. Reprinted with permission from the American Chemical Society.

7, Appendix D, getch()

Figure 8.7. Schematic illustration of mesogen and smectic layer orientations of surface-grafted polymer (left) and spincast (right) thin lms of LC Az polymer.

killchar()

25.09.2004 21:11

The killchar() function returns the character that currently serves as the terminal s Killchar, or KILL, key.

In the surface-grafted LC polymer lm, thermophysical properties are similar to those of a spincast lm. The in-plane orientation of Az groups in the surfacegrafted polymer lm may lead to different photoresponsive nature in the lm. Since the photoresponsive mesogens are oriented parallel to the substrate plane, the lm may be more sensitive to the polarization of LPL. In fact, LPL induces stronger in-plane anisotropy in the surface-grafted lm than in the ordinary cast lm. It is anticipated that this newly designed light-responsive surface may nd many new opportunities and applications.

char killchar(void);

Invocation Asynchrony Patterns but the invocation is performed asynchronously without making the client wait for a result.

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