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almost negligible. Polarized optical microscopy indicates the in-plane orientation of the dye aggregates over large areas. The spectroscopic data and in-plane XRD measurements indicate that the B67 molecules are stacked to form a column where the planar B67 molecules (light absorption transition moment) are stacked orthogonal to the column direction. The structure of the photoaligned B67 and columns are schematically indicated in Fig. 8.5. The molecular axis of B67 coincides with the direction of photooriented mesogens (parallel to LPL) of PPLC lm, and therefore, the columns are extended orthogonal to the LPL direction. The orientation of the chromonic columns of B67 aligned by the LPLirradiated PPLC lm exactly agrees with that of rodlike micelles formed by ordinary surfactant aggregates (Fukumoto et al., 2006). However, the dip coating procedure without LPL irradiation obviously brings about macroscopic alignment of the B67 columns along the lifting direction (Hara et al., 2007). The macroscopic alignment should stem from the ow orientation in this case. On the basis of these facts, micropatterning of the chromonics silica hybrid can be attained utilizing a combination of photo- and ow orientation. A patterned irradiation with LPL onto the PPLC lm is made through a photomask, and then the dip coating is achieved to prepare the chromonic silica hybrid lm. In this procedure, the directions of LPL and dipping are arranged to be consistent so that the orientation of the columns in the regions of irradiated and nonirradiated areas become orthogonal with each other.



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The statement sets the text input delay to one second. When getch() has not received input after one second, it returns ERR.

bytes := marshal(i) send(bytes)





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For the synthesis of azobenzene-containing amphiphilic BCPs, the most used method, which is also the most convenient one, is the atom transfer radical polymerization (ATRP). The rst work was reported in 2002 by Tian et al. who used a hydrophilic poly(ethylene oxide) (PEO) macroinitiator to grow a hydrophobic block of poly{11-[4-(4-butylphenylazo)phenoxy]undecyl methacrylate} that is a side-chain liquid crystalline (LC) polymer (SCLCP) (structure a in Fig. 6.2) (Tian et al., 2002). Even though this amphiphilic BCP was not synthesized and investigated for its self-assembly behavior in solution, PEO is actually a good choice as the hydrophilic block for BCP micelles having interest for possible biomedical applications. PEO is highly soluble in water, enables steric stabilization of the micelle and can inhibit the surface adsorption of biological substances, thus protecting the loaded guest (Kang et al., 2005). Following this work, a number of amphiphilic azobenzene BCPs have been synthesized using PEO macroinitiators with different azobenzene polymers (Ding et al., 2008; Yu et al., 2007a,b, 2006a,b;

timeout(-1);

The statement activates (or reactivates) the blocking nature of text input functions such as getch(). This could be used in a program to reset a previously set timeout() value.

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Sin et al., 2005; Yu et al., 2005). Using a dibromo initiator, a dibromo PEO macroinitiator (Br-PEO-Br) was prepared and subsequently employed to grow an azobenzene polymer, yielding an amphiphilic ABA-type triblock copolymer (Tang et al., 2007). When other water-soluble polymers are used as the hydrophilic block, the direct synthesis of the hydrophilic macroinitiator using ATRP may be problematic, in contrast to PEO. For instance, ATRP cannot be used to prepare a poly(acrylic acid) macroinitiator because of the reaction between the monomer and the metal complexes (Patten and Matyjaszewski, 1998). The general approach employed to bypass the problem is to synthesize rst a diblock copolymer that is not amphiphilic and, subsequently, convert one block into the desired hydrophilic polymer through a postreaction. As a matter of fact, the rst light-controllable azobenzene BCP micelle was demonstrated using a BCP whose hydrophilic block was obtained in this fashion (structure b in Fig. 6.2) (Wang et al., 2004). A macroinitiator of poly(tert-butyl acrylate) (PtBA) was rst synthesized and then used to grow poly{6-[4-(4-methoxyphenylazo)phenoxy]hexyl methacroylate} (PAzoMA). The resulting diblock copolymer PtBA-b-PAzoMA was rendered amphiphilic by subsequent hydrolysis of PtBA giving rise to the hydrophilic poly(acrylic acid) (PAA). The selective cleavage of tBA groups is possible because

5 int main(void) 6 { 7 int ch; 8 9 initscr(); 10 11 timeout(DELAY); 12 printw( The timeout delay has been set to %d ; milliseconds.\n ,DELAY); 13 addstr( Try to type in your name fast enough:\n ); 14 refresh(); 15 16 do 17 { 18 ch = getch(); 19 if(ch == \n ) 20 break; 21 } while(ch != ERR); 22 23 mvaddstr(5,0, Hope you got it all in! ); 24 refresh(); 25 getch(); 26 27 endwin(); 28 return 0; 29 }

The next sequence diagram shows an example of SYNC WITH SERVER. Again there are two variants, one using network facilities and the other using multithreading, although now on the server side. We show both alternatives in turn, starting with the variant that uses network facilities. In this case we carry out a normal synchronous method invocation. However, the CLIENT REQUEST HANDLER only waits

Sample output:

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