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1.1.3.2. Liquid Crystals. Azobenzenes are anisotropic, rigid molecules and as such are ideal candidates to act as mesogens: molecules that form LC mesophases. Many examples of small-molecule azobenzene liquid crystals have been studied. Some azo polymers also form LC phases (refer to Fig. 1.6 for a typical structure). For side-chain azobenzenes, a certain amount of mobility is required for LC phases to be present; as a rule, if the tether between the chromophore and the backbone is less than 6 alkyl units long, the polymer will exhibit an amorphous and isotropic solid-state phase, whereas if the spacer is longer, LC phases typically form. The photoisomerization of azobenzene leads to modi cation of the phase and alignment (director) in LC systems (Shibaev et al., 2003; Ichimura, 2000). The director of a liquid crystal phase can be modi ed by orienting chromophores doped into the phase (Sun et al., 1992; Anderle et al., 1991) by using an azobenzene-modi ed command surface (Chen and Brady, 1993; Ichimura et al., 1993; Gibbons et al., 1991), using azo copolymers (Wiesner et al., 1991), and, of course, in pure azobenzene LC phases (Hvilsted et al., 1995; Stumpe et al., 1991). One can force the LC phase to adopt an in-plane order (director parallel to surface), homeotropic alignment (director perpendicular to surface), tilted or even biaxial orientation (Yaroschuk et al., 2001). These changes are fast and reversible. Although the trans-azobenzenes are excellent mesogens, the cis-azos typically are not. If even a small number of azomolecules are



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If the terminal does not have the ability to insert and delete characters, then it will be provided by NCurses in software. The insch() function is used to insert a character on the screen. The delch() function deletes a character. The idcok() function is used to switch between hardware and software modes for inserting and deleting characters. See idcok(). This is one of several NCurses functions that report back information on the terminal. The others include baudrate(), erasechar(), killchar(), has_il(), longname(), termattrs(), and termname().

Process C 3) lookup( someName ) Absolute Object Ref Client 4) invoke an operation Machine Boundary Process A Lookup Machine Boundary Process B Server Application 2) bind( someName, GlobalObjectReference) Remote Object

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distributed in an LC phase, trans-cis isomerization can destabilize the phase by lowering the nematic-to-isotropic phase transition temperature (Eich and Wendorff, 1990) This enables fast isothermal photocontrol of phase transitions (Kato et al, 1996; Hayashi et al, 1995; Ikeda and Tsutsumi, 1995; Ikeda et al, 1990) Since these modulations are photoinitiated, it is straightforward to create patterns (Shannon et al, 1994) These LC photoswitching effects are obviously attractive in many applications, such as for display devices, optical memories (Gibbons et al, 1991), electro-optics (Luk and Abbott, 2003), and modulating the polarization of ferroelectric liquid crystals (Fischer et al, 1997; Ikeda et al, 1993) 1133 Dendrimers Dendrimers have been investigated as unique structures to exploit and harness azobenzene s photochemistry (Momotake and Arai, 2004a,b; Villavicencio and McGrath, 2002).

1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 #include <ncurses.h> int main(void) { initscr(); addstr( This terminal ); if(has_ic()) addstr( has ); else addstr( does not have ); addstr( insert/delete character abilities ); refresh(); getch(); endwin(); return 0; }

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The server application binds the reference of a remote object to a symbolic name in the lookup service after instantiating the remote object. The client looks up the ABSOLUTE OBJECT REFERENCE using the same symbolic name, gets the reference returned, and finally invokes an operation on the remote object.

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Dendritic and branched molecular architectures can have better solubility properties and can be used to control undesired aggregation, resulting in higher quality lms for optical applications (Campbell et al, 2006; Ma et al, 2002) Dendrimers with strongly absorbing pendants can act as antenna, harvesting light and making it available, via intramolecular energy transfer, to the dendrimer core In dendrimers with azo cores, this allows for the activation of isomerization using a wavelength outside of the azo-absorption band (since the dendrimer arms absorb and transfer energy to the core) (Aida et al, 1998; Jiang and Aida, 1997) Furthermore, the con gurational change that results from the core isomerization will translate into a larger scale geometric change For instance, in a dendrimer with three azobenzene arms (Fig 1.

Also, the NCURSES.H file defines such things as TRUE, FALSE, OK, ERR, and other useful constants. It contains definitions for structures you ll be using later. Plus, it includes many other wonderful and useful goodies. If you have the time, peruse the header file, which can be found at /USR/INCLUDE/ NCURSES.H.

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