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SEM observation found that only large micelle-like aggregates (B200 nm) coexisting with core shell micelles (B15 nm) were formed by adding water into the dioxane solution; UV and visible light irradiation only resulted in changes in the number of the aggregates (Wang et al, 2004) This result suggests that a large increase in dipole moment of azobenzene moieties on the hydrophobic block upon UV irradiation is necessary but may not be enough to lead to the dissociation of micellar aggregates The same increase in dipole moment for azobenzene mesogens takes place in the two samples upon UV light irradiation, but for P(tBA19-co-AA33)-b-PAzoMA31, the resulting increase in polarity of the PAzoMA block is not important enough to alter signi cantly the hydrophilic hydrophobic balance because of the stronger hydrophilicity of the P(tBA-co-AA) block.



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Listing 10-4 (continued)

Web Services Technology Projection Now we can further compose handlers into chains:

15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46





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Therefore, it appears that the prominent light-induced dissociation and reformation observed for the vesicles of P(tBA46-co-AA22)-b-PAzoMA74,were the result of an increase in polarity of the hydrophobic PAzoMA block in conjunction with the weakness of hydrophilicity of the hydrophilic block (the relative length and chemical nature) Under such a conjugation, the reversible trans cis isomerization of azobenzene moieties can alter reversibly the hydrophilic hydrophobic balance in the two directions, which determines the state of aggregation of the diblock copolymer Strictly speaking, the origin of the observed effect is more complicated than it may appear to be The difference between the two BCP samples may come not only from the difference in composition of the two blocks, but can also be contributed by the different compositions of the P(tBA-co-AA) blocks, which actually changes the chemical nature of the hydrophilic block.

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lister = newwin(maxy,maxx/2,0,maxx/4); if( lister == NULL) { addstr( unable to create window\n ); refresh(); getch(); endwin(); return(1); } /* open the file */ text = fopen(FILENAME, r ); if( text == NULL ) { addstr( unable to open file\n ); refresh(); getch(); endwin(); return(2); } /* display the file s contents */ do { ch = fgetc(text); waddch(lister,ch); wrefresh(lister); } while (ch != EOF); fclose(text); getch(); endwin(); return(0); }

In order to disclose the effect of BCP composition, it would be more straightforward to utilize BCPs that differ only in the relative lengths of the two blocks, such as PAA-b-PAzoMA.

Either chains or individual handlers can be used in service descriptions. We can put the handler into the request flow, the response flow, or both, for example:

This program creates a new window, lister. The window is half the width of the standard screen, but just as tall. A file is opened on disk and displayed, character by character, in the window. The notion here is to display enough text that the window needs to scroll to display the whole thing. Note that the filename is defined in line 3. I m using the text from Lincoln s Gettysburg Address, which is saved in the same folder as SCROLLER.C and in a file named GETTYSBURG.TXT. Be sure to specify the name of an existing text file in line 3; the file must contain enough text to require the window to scroll to display it all. Breaking with tradition here, I m doing some error-checking in this program, both for creating the new window as well as opening the file. And... it doesn t scroll. Instead, after the window is filled, remaining text in the file continues to be plugged in to the bottom-most, right character position in window lister.

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Figure 6.8. (a) Transmittance vs. water content added to the dioxane solution of P(tBA46-co-AA22)-b-PAzoMA74 (initial concentration, 1 mg mL 1) without and with UV irradiation. (b) Transmittance vs. water content added to the tetrahydrofuran solution of P(tBA46-co-AA22)-b-PAzoMA74 (initial concentration, 1 mg mL 1) without and with UV irradiation. (c) Transmittance vs. water content added to the dioxane solution of P(tBA19-co-AA33)-b-PAzoMA31 (initial concentration, 1 mg mL 1) without and with UV irradiation. Source: Tong et al., 2005.

Enabling scrolling in NCurses is easy, thanks to the scrollok() function:

<service name="DateService" provider="java:RPC"> ... <requestFlow> <handler type="myChain"/> </requestFlow> </service>

scrollok(win,TRUE);

or PEO-b-PAzoMA. Moreover, the effect of BCP composition is related to the used solvent. The more the increase in polarity of the hydrophobic block due to the trans cis isomerization of azobenzene reduces the difference in solubility of the two blocks in a given solvent, the more ef cient the photoinduced dissociation of the micellar aggregates should be.

The scrollok() function sets or resets the ability of a window to scroll. The window is specified as win, and the second argument is either TRUE or FALSE to turn scrolling on or off (respectively) for that window. Add the following at line 23:

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