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Photochromic molecule changes its polarity (dipole moment) by light, and this property has long been applied to photocontrollable wetability changes of liquids. This is still an active area of investigation (Lim et al., 2007; Ichimura et al., 2000). In cases of anisotropic liquids, namely, thermotropic LCs, the molecular orientation is readily controlled on a photoresponsive monolayer. A pioneering work was reported by Ichimura et al. (1988) (Seki et al., 1993). They showed that the trans cis photoisomerization reaction of an Az monolayer can reversibly switch the alignment of nematic LCs, and proposed a concept of command surface effect. Recent attempts by Seki and coworkers revealed that photoalignment of organized materials is not limited to typical thermotropic LCs, but a certain polymer (Fukuda et al., 2002a,b; Seki et al., 1999) and even an anisotropic structure of inorganic organic hybrid materials (Fukumoto et al., 2006, 2005; Kawashima et al., 2004, 2002) are controlled by light. The in-plane control utilizes the angular selective reaction of photoreactive units by irradiation with linearly polarized light (LPL) followed by the ordering owing to the cooperative self-assembling (Seki, 2007, 2004; Ikeda, 2003; Natansohn and Rochon, 2002; Ichimura, 2000).



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1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 #include <ncurses.h> int main(void) { initscr(); addstr( Tabs set naturally:\n ); addstr( A\tB\tC\tD\tE\tF\tG\tH\tI\tJ\tK\tL\tM\n ); addstr( Tab stop set to 5\n ); TABSIZE = 5; addstr( A\tB\tC\tD\tE\tF\tG\tH\tI\tJ\tK\tL\tM\n ); refresh(); getch(); endwin(); return 0; }

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A vast amount of investigations on photoalignment of LCs has been reported during the past one and a half decades. Irradiation with LPL induces photoinduced anisotropy, in which molecules are generally oriented to an unexcitable direction, namely, perpendicular to the electric vector of the polarization direction. This effect is called photoinduced optical anisotropy (Seki, 2004; Natansohn and Rochon, 2002; Ichimura, 2000). Exposure of the 6Az10-poly(vinyl alcohol) (PVA) monolayer to LPL induces an in-plane orientation of the Az side chain orthogonal to the polarization plane of LPL. A spincast lm of poly(di-n-hexylsilane) (PDHS) is subsequently prepared onto this photooriented Az monolayer (scheme shown in Fig. 8.1, left). After

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application has nothing to do with the specifics of result handling in the client. The use of RESULT CALLBACKS requires an event-driven application design, whereas POLL OBJECTS allow a synchronous programming model to be used. The RESULT CALLBACK pattern also incurs the liability that client code, namely the code doing the original asynchronous invocation and the code associated with the RESULT CALLBACK, is often executed concurrently in multiple thread contexts. The client code therefore needs to be prepared for that, for example when accessing shared resources. To dispatch replies to callback objects, the client side distributed object

Tabs set naturally: A B C I J K L M Tab stop set to 5 A B C D E D E F G H ;

Figure 8.1. Photoalignment of PDHS lm by an LPL-irradiated photoresponsive Az monolayer. Schematic illustration of the system (left) and topological AFM image (right).

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middleware needs an separate thread besides the client's thread invoking the original invocation. Typical implementations require the client to provide a callback object as a remote object, which is registered with the client-side distributed object middleware on invocation of an asynchronous operation. There are two implementation options: The client-side distributed object middleware invokes the callback object when the result of the operation arrived. The server-side distributed object middleware invokes the callback object, typically using a new connection that sends an independent reply message. In the second case, the client has to become a server as well, as it has to accept invocations on the callback object. The remote callback can become a problem in configurations in which a firewall exists between client and server: callback invocations using a new connection for the callback might get blocked by the firewall. The use of bidirectional connections is therefore advisable to allow requests to flow in both directions without requiring new connections. The major difference between POLL OBJECT and RESULT CALLBACK is that RESULT CALLBACKS require an event-driven design, whereas POLL OBJECTS allow large parts of the client be written using a synchronous execution model, thus hiding the subtleties of asynchrony from the developer.

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