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Repeat the calculations of Exercise 5.3 for this set of data, which corresponds to the start of experiment 3T of Arnold and Toor (1967). 5.5 McKay (1971) carried out experiments in a Loschmidt-type diffusion cell with a nine component system including nitrogen, carbon dioxide, and a number of paraffins. The experiments were carried out at the high temperatures and pressures typical of underground oil and gas reservoirs. McKay's paper includes a dimensioned drawing of the Loschmidt-type cell used for the experiment and the initial conditions for some of his experiments. Use the theory of Section 5.5 to predict the composition profiles in this system. State clearly any assumptions made in your calculations. You will need to estimate diffusion coefficients at high pressure. Consult Reid et al. (1987) for details of methods that can be used for this purpose. 5.6 Consider interphase mass transfer in the system glycerol(l)-water(2)-acetone(3). In a particular equilibration experiment carried out by Krishna et al. (1985) the initial composition in the acetone-rich phase is x10 = 0.85 The composition of the interface is xu = 0.5480 x2I = 0.2838 x3I = 0.1682. x20 = 0.15 x30 = 0.0





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