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Rating 4.0 low-molecular-weight tectonic unit is shown in Fig. 2.3. For the rst time, this approach was realized for photosensitive polymer azobenzene unit complexes using ionic interaction (Fig. 2.2d) (Meyer et al., 1991) and H-bonding (Fig. 2.4a) (Kato et al., 1996), where nonlinear optical properties and in uence of UV-vis irradiation on a reversible isothermal nematic isotropic phase transition have been investigated, respectively. The development of H-bonded complexes is now considered. An in uence of UV irradiation on optical properties of low-molecular-weight azobenzene-containing material (Fig. 2.4b) has been investigated (Aoki et al., 2000) on the basis of such interactions. The rst observation of photoinduced optical anisotropy in Hbonded complexes of azobenzene dyes and copolymers (Fig. 2.4b) has been recently demonstrated (Medvedev et al., 2005). In this case, the induced anisotropy was stable, and the maximum dichroic ratio of 2 has been observed. A kinetics of the induction of birefringence (maximum value of ca. 0.01) in one of these complexes is shown in Fig. 2.5. An in uence of H-bonding on the mesomorphic and photoorientation properties was recently demonstrated (Cui and Zhao, 2004). In this approach, the amorphous azopyridine side-chain polymer was converted into liquid crystalline polymers through self-assembly with a series of commercially available, aliphatic, and aromatic carboxylic acids (Fig. 2.4d). adobe pdf editing software free download Download Pdf Editor for Windows 7 - Best Software & Apps - Softonic
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