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assembly produced by an electrostatic LbL technique. LbL deposition was introduced in the early 1990s (Lvov et al., 1993) and has since gained a great popularity in the fabrication of thin lms of different materials from simple ionic species to colloidal particles and biological macromolecules (Hammond, 2000; Decher et al., 1998). These solid lms consist of adjacent layers of oppositely charged polyelectrolytes and different other low molecular materials, nanoparticles, colloids, etc. In this case, ionic interaction is not only used to form a molecular complex but also results in layered structure at a molecular level. The lms are manufactured by subsequent dipping of a substrate in solutions of these oppositely charged species (Fig. 2.6). According to the authors, LbL lms, which are self-assembled layered structures, could be considered as solid-state supramolecular complexes formed by ionic interactions. Azobenzene-containing materials also found their place with this popular technique and could be divided from chemical point of view to azobenzene-containing polyelectrolytes (Aldea et al., 2007; He et al., 2004; Wang et al., 2004a,b, 1998; Zucolotto et al., 2004b, 2002; Wu et al., 2001; Lee et al., 2000; Balasubramanian et al., 1998; Lvov et al., 1997), with azobenzene moieties in main- or side chain, and low-molecular-weight azobenzene derivatives (Zucolotto et al., 2003; dos Santos et al., 2002; Shinbo et al., 2002; Ziegler et al., 2002; Dragan et al., 2001; He et al., 2000; Advincula et al., 1999; Saremi and Tieke, 1998); some of them are conventional ionic azodyes. The requirement and restriction to azodye in this method is a presence of at least two charged groups to be able to bind to oppositely charged sites in the polyelectolyte chains from two different adjacent layers (Fig. 2.6). As second nonactive component, usual polyelectrolytes such as PDADMAC, PAH, PEI,



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The derwin() function is used to create a subwindow, similar to the subwin() function though derwin() places the subwindow relative to the parent window, not the screen.

[FGM+97]

A 1 2

WINDOW *derwin(WINDOW *orig, int nlines, int ncols, int begin_y, int begin_x);

orig is a pointer to a window. That window then becomes the parent of the subwindow derwin() creates. nlines and ncols are int values that set the subwindow s size in rows and columns, respectively. Values range from 1 on up, though the window created cannot be taller or wider than the screen or its parent. When 0 is specified for nlines or ncols, then the subwindow extends to the bottom or right edge of the window, respectively.

Figure 2.6. Schematic illustration of the preparation of alternate polycation polyanion multilayer assemblies onto a negatively charged substrate.

[FHA99] [FHF+01]





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begin_y and begin_x give the subwindow s origin relative to the parent window. Values for begin_y and begin_x are ints, ranging from 0, 0 (the upper-left corner of the parent window) to the maximum number of rows and columns for the parent window minus the size of the subwindow.

Upon success, a WINDOW pointer is returned, used to reference the subwindow. On failure, NULL is returned. (See NULL.)

Figure 7.1. Structures of azo-modi ed polymers (here random copolymers) that have been used in solution to trigger phase separation, physical gelation, or photoswelling of chemical gels. n = 5 11 (Pouliquen and Tribet, 2006); R1 = CH3 and R2 = H (Irie, 1993); or R1 = H and R2 = H, methyl, ethyl, or butyl (Howley et al., 1997).

The main difference between derwin() and subwin() is in the arguments that set the window s original. In the derwin() call, the coordinates are relative to the parent window; in subwin() the coordinates are relative to the standard screen. Aside from the one difference in the origin coordinates, subwin() and derwin() are pretty much the same. Refer to the entry for subwin() for a host of notes that also apply to derwin().

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[Fip04]

subby = derwin(main,MAXY-2,MAXX-2,1,1);

Phase separation and demixing of a polymer from its solution has attracted much attention because of technological importance in coating and encapsulation. Basically, the tendency to demix comes from the weak translational entropy gained upon dissolution of long polymer and macrocomplexes. Phase separation is accordingly achieved when the monomer-solvent interaction energy (namely, the enthalpy of dilution) does not provide strong driving force toward solubilization. The solubility transition takes place abruptly on decreasing the solventmonomer attraction and can be recognized as a critical transition for in nitely long chains. For this reason, precipitation of stimuli-responsive macromolecules is triggered by relatively weak variations of variable parameters such as temperature, solvent composition (pH, salt), and E Z isomerization of azobenzene-containing monomers. In practice, the enthalpy of solvatation, speci cally of azo monomers, varies with photoswitch of polarity and conformation, because the E and Z states display different Van der Waals and hydrophobic interactions. In turn, lightresponsive aggregation or collapse of chains is achieved (Fig. 7.2a). More complicated responses to light have been achieved by mixing the polymers with molecules or nanoparticle that can associate with the azo groups. The phase transition of simple polymer/solvent systems is described in Section 7.2.1 and the case of complexes with cyclodextrins (CDs) or surfactants is discussed in Sections 7.2.2 and 7.2.3.

This statement creates a subwindow subby within the parent window main. The size of subby is equal to MAXY-2 rows by MAXX-2 columns, and subby s upper-left corner is set down at row 1, column 1 of the window main.

[FKT01]

Temperature or quality of solvent (b)

1 2 3 4 5 6 7 8 9 10 11 12 13 #include <ncurses.h> int main(void) { WINDOW *pops,*sonny; int x2,y2,x4,y4; initscr(); start_color(); init_pair(1,COLOR_WHITE,COLOR_BLUE); init_pair(2,COLOR_RED,COLOR_YELLOW); x2 = COLS >> 1; y2 = LINES >> 1;

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