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The refresh() function is used to update the screen in NCurses. Most NCurses output functions require that refresh() be used so that you can see the output on the terminal display.

In NCurses, there is the virtual window that exists in memory and then the current screen, which is what s shown on the screen. What the refresh() function does is to check to see which parts of a window have been touched (changed) since the last refresh(), then those parts of the window are written to the current screen during the next refresh() operation.



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Azobenzene and its derivatives have been extensively used as dyestuffs, pigments, and pH indicators for a long time (Zollinger, 1991). It is well known that azobenzene can exist as trans or cis isomers in the electronic ground state (Rau, 1990). The trans isomer can be converted into cis isomer upon UV light (365 nm) irradiation. The cis-to-trans isomerization readily occurs at room temperature and can be further accelerated by heating or stimulated by visible light irradiation. The trans cis isomerization mechanism and related problems have been intensively investigated by both theoretical calculations and experimental analyses for several decades (see, e.g., Cembran et al., 2004; Schultz et al., 2003; Ishikawa et al., 2001; Cattaneo and Persico, 1999). For the photoisomerization, the transition is related to the motion out of the Franck Condon range on the potential energy surfaces (PESs) of the excited states. Two possible mechanisms of the isomerization have been proposed and tested by different methods. In typical cases, the rotation mechanism attributes the isomerization to the twist around the CNNC dihedral angle, whereas the inversion mechanism ascribes the isomerization to the inversion of one or both of the CNN angles through a linear transition state (Chang et al., 2004; Rau, 1990). Substitution on azobenzene can signi cantly affect the energy gap between the ground and exited states and the isomerization pathways (Crecca and Roitberg, 2006; Schmidt et al., 2004; Biswas et al., 2002; Astrand et al., 2000). The former causes the azobenzene derivatives to possess absorption bands at different wavelengths and exhibit many different hues as dyestuffs and pigments.





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int refresh(void); int wrefresh(WINDOW *win);

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The function has no arguments. Refer to the w entry elsewhere in this appendix for information on the win argument.

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Next to getch(), refresh() is the most often used function in NCurses. Internally, the refresh() function is a combination of wnoutrefresh() and doupdate() calls. It s possible that refresh() alone may not properly update the screen. If so, consider using the clearok() function before calling refresh(). Also see the touchwin() function. When you are using the following combination:

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The latter can result in a variety of expected and unexpected isomerization behaviors The problems such as the stable conformation, PESs of the excited states, and isomerization mechanism of the azo compounds are still being explored as active research frontiers Some puzzling problems as debatable issues still remain in subjects even after persistent study for years Interested readers can nd more comprehensive reports on these issues in some recent publications (see, eg, Diau, 2004; Satzger et al, 2004) For real applications, isomerization that can cause color change for dyestuffs had more or less been considered as an unfavorable factor in history for a long time (Zollinger, 1961) Signi cant effort was devoted to prevent the isomerization through some improved molecular designs This situation has been dramatically changed after early efforts to covalently introduce azobenzene-type chromophores into polymeric chains (Kumar and Neckers, 1989).

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