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339 Use the Soave/Redlich/Kwong equation to calculate the molar volumes of saturated liquid and saturated vapor for the substance and conditions given by one of the parts of Pb 338 and compare results with values found by suitable generalized correlations 340 Use the PengRobinson equation to calculate the molar volumes of saturated liquid and saturated vapor for the substance and conditions given by one of the parts of Pb 338 and compare results with values found by suitable generalized correlations 341 Estimate the following: (a) The volume occupied by 18 kg of ethylene at 32815 K (55 C) and 35 bar (b) The mass of ethylene contained in a 025-m3 cylinder at 32315 K (50 C) and 115 bar 342 The vapor-phase molar volume of a particular compound is reported as 23 000 cm3 mol-' at 300 K and 1 bar No other data are available Without assuming ideal-gas behavior, determine a reasonable estimate of the molar volume of the vapor at 300 K and 5 bar 343 To a good approximation, what is the molar volume of ethanol vapor at 75315 K (480 C) and 6000 kPa How does this result compare with the ideal-gas value 344 A 035-m3 vessel is used to store liquid propane at its vapor pressure Safety considerations dictate that at a temperature of 320 K the liquid must occupy no more than 80% of the total volume of the vessel For these conditions, determine the mass of vapor and the mass of liquid in the vessel At 320 K the vapor pressure of propane is 160 bar 345 A 30-m3 tank contains 14 m3 of liquid n-butane in equilibrium with its vapor at 29815 K (25 C) Estimate the mass of n-butane vapor in the tank The vapor pressure of n-butane at the given temperature is 243 bar 346 Estimate: (a) The mass of ethane contained in a 015-m3 vessel at 33315 K (60 C) and 14 bar (b) The temperature at which 40 kg of ethane stored in a 015-m3 vessel exerts a pressure 20 bar 347 To what pressure does one fill a 015-m3 vessel at 29815 K (25 C) in order to store 40 kg of ethylene in it.



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348 If 15 kg of H 2 0 in a 04-m3 container is heated to 67315 K (400 C), what pressure is developed 349 A 035-m3 vessel holds ethane vapor at 29815 K (25 C) and 2200 kPa If it is heated to 49315 K (220 C), what pressure is developed 350 What is the pressure in a 05-m3 vessel when it is charged with 10 kg of carbon dioxide at 30315 K (30 C) 351 A rigid vessel, filled to one-half its volume with liquid nitrogen at its normal boiling point, is allowed to warm to 29815 K (25 C) What pressure is developed The molar volume of liquid nitrogen at its normal boiling point is 347 cm3 mol-' 352 The specific volume of isobutane liquid at 300 K and 4 bar is 1824 cm3 g l Estimate the specific volume at 415 K and 75 bar 353 The density of liquid n-pentane is 0630 g cmP3at 29115 K (1 8 C) and 1 bar Estimate its density at 41315 K (140 C) and 120 bar 354 Estimate the density of liquid ethanol at 45315 K (180 C) and 200 bar 355 Estimate the volume change of vaporization for ammonia at 29315 K (20 C) At this temperature the vapor pressure of ammonia is 857 kPa 356 P V T data may be taken by the following procedure A mass rn of a substance of molar mass M is introduced into a thermostated vessel of known total volume V t The system is allowed to equilibrate, and the temperature T and pressure P are measured ( a ) Approximately what percentage errors are allowable in the measured variables (m, M , V f ,T and P ) if the maximum allowable error in the calculated compressibility factor Z is fl% (b) Approximately what percentage errors are allowable in the measured variables if the maximum allowable error in calculated values of the second virial coefficient B is fl% Assume that Z E 09 and that values of B are calculated by Eq (332) 357 For a gas described by the RedlichIKwong equation and for a temperature greater than T,, develop expressions for the two limiting slopes,.

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