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Appreciable negative departures from P-xl linearity reflect stronger liquid-phase intermolecular attractions between unlike than between like pairs of molecules Conversely, appreciable positive departures result for solutions for which liquid-phase intermolecular forces between like molecules are stronger than between unlike In this latter case the forces between like molecules may be so strong as to prevent complete miscibility, and the system then forms two separate liquid phases over a range of compositions, as described in Sec 144 Since distillation processes are carried out more nearly at constant pressure than at constant temperature, t-xl-y, diagrams of data at constant P are of practical interest The four such diagrams corresponding to those of Fig 108 are shown for atmospheric pressure in Fig 109 Note that the dewpoint (t-yl) curves lie above the bubblepoint (t-xl) curves Moreover, the minimum-pressure azeotrope of Fig 108(b) appears as a maximum-temperature (or maximum-boiling) azeotrope on Fig 109(b)There is an analogous correspondence between Figs 108(d) and 109(d) The yl-xl diagrams at constant P for the same four systems are shown in Fig 1010 The point at which a curve crosses the diagonal line of the diagram represents an azeotrope, for at such a point yl = XI



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7:

1326 Consider the gas-phase oxidation of ethylene to ethylene oxide at a pressure of 1 bar with 25% excess air If the reactants enter the process at 29815 K (2S C),if the reaction proceeds adiabatically to equilibrium, and if there are no side reactions, determine the composition and temperature of the product stream from the reactor 1327 Carbon black is produced by the decomposition of methane:

When handling a bomb threat on the telephone: A Warn the caller of existing BIP B Hang up; most bomb threats are hoaxes C Keep the caller talking to receive as much information as possible D Tell the caller to notify the police

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For equilibrium at 92315 K (650 C) and 1 bar, (a) What is the gas-phase composition if pure methane enters the reactor, and what fraction of the methane decomposes (6) Repeat part (a) if the feed is an equimolar mixture of methane and nitrogen

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1328 Consider the reactions,

If a written threat is received: A Throw it out; most written threats are a hoax B Don t take it lightly; any bomb threat is serious C Save all material, along with envelopes or containers D B and C above

If these reactions come to equilibrium after combustion in an internal-combustionengine at 2000 K and 200 bar, estimate the mole fractions of NO and NO2 present for mole fractions of nitrogen and oxygen in the combustion products of 070 and 005

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1329 Oil refineries frequently have both H2S and SO2 to dispose of The following reaction suggests a means of getting rid of both at once:

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Table Owner DV812FA DV812FA DV812FA DV812FA DV812FA DV812FA DV812FA DV812FA DV812FA DV812FA DV812FA DV812FA DV812FA DV812FA DV812FA

101 Different alarm systems are incompatible and should never become part of an integrated system A True 102 B False

For reactants in the stoichiometric proportion, estimate the percent conversion of each reactant if the reaction comes to equilibrium at 72315 K (450 C)and 8 bar

Now that you have activated the package, you are ready to begin the package build process Click the Submit Build button (this launches the R9621 Package Build report, which will run locally) In this section, we are going to cover what happens when this UBE runs NOTE With the E812 version of the software, Oracle moved from a TAM (Table Access Management) format creating two files per specification (a ddb and a xdb) to an XML specification file; this creates a table for each spec file The client stores these tables in the Microsoft SQL Server Desktop Engine (MSDE) or SQL Server Express (SSE) database, and the server build stores them on the database

1330 The species N2O4and NO2 as gases attain rapid equilibrium by the reaction:

FIGURE 7-12 Package Build Revisions window (P9621/W9621B)

When a photocell alarm system will not arm, this is most likely caused by: A Improper installation B A blockage of the beam C Cut wires D None of the above

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