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The gammdphi approach to VLE calculations, based on Eq (14 l), presumes knowledge of the vapor pressure of each species at the temperature of interest Situations do arise however where a species is either unstable at the system temperature or is supercritical, ie, the system temperature exceeds its critical temperature Therefore its vapor pressure cannot be measured, and its fugacity f i as a pure liquid at the system temperature cannot be calculated by Eq (1141) Consider a binary system wherein species 1, designated the solute, cannot exist as a pure liquid at the system temperature Although Eqs (141) and (142) can be applied to species 2, designated the solvent, they are not applicable to the solute, and an alternative approach is required Figure 146 shows a typical plot of the liquid-phase fugacity of the solute f l vs its mole fraction xl at constant temperature This figure differs from Fig 123 in that the curve representing f l does not extend all the way to xl = 1 Thus the location of fi, the liquid-phase fugacity of pure species 1, is not established, and the line representing the LewisRandall rule cannot be drawn The tangent line at the origin, representing Henry's law (Sec 121), provides alternative information Recall that the slope of the tangent line is Henry's constant, defined by Eq (122) Thus,



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The tables associated with the data dictionary include the following in the central repository:

XI-0

Security personnel should have access to a current list (including resident telephone numbers) of key individuals and organizations that would be involved in the activation of a disaster plan This list should include: A Corporation department heads B All employees C The police and fire departments D A and C above

F00165 (Media Objects Storage) F9200 (Data Item Master) F9202 (Data Field Display Text) F9203 (Data Item Alpha Descriptions) F9207 (Data Dictionary Error Message Information) F9210 (Data Field Specifications) F9211 (Data Dictionary Smart Fields) F9212 (Smart Field Criteria-Setup Rules) F9755 (Change Table Data Item Master) F9757 (Change Table Data Item Alpha Description) F9760 (Change Table OneWorld Data Field Specification)





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Henry's constant is a strong function of temperature, but only weakly dependent on pressure Note, however, that the definition of X l at temperature T presumes the pressure is the equilibrium value at xl -+ 0, ie, the vapor pressure of the pure solvent Ppt

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We ll start with the F9200 table (Data Item Master), and work our way forward as we gain a better understanding of what is in the data dictionary The F9200 table is the header information for each data item and includes the data item name, its system code, and its reporting code It also contains some audit data, including the user ID of the user who either added or modified the data dictionary item last, the machine the change was issued from, and when the change occurred The next table we should discuss is F9202 (Data Field Display Text) It contains a language identifier and several different columns for descriptions and fieldsensitive help The next table is F9203 (also known as Data Item Alpha Descriptions) It maintains descriptions used in both the data dictionary searches and the Object Librarian records The next table up for discussion is the F9207 table (Data Dictionary Error Message Information) It is important to note that all error messages displayed in EnterpriseOne originate from this table Many organizations decided to modify these error messages to make more sense for their specific implementation of the product The next table is the F9210 table (Data Field Specifications) This defines each data item in detail, including the type of field, the number of decimal places, and so on This is the real information behind the data dictionary item definitions and can be considered the detail lines to F9200 s header information The next table we ll discuss with regard to the data dictionary is F9211 (Data Dictionary Smart Fields) Smart fields are data dictionary items that are associated with specific business functions An example might be a smart field in a UBE drilldown report that summarizes data from multiple places for the end user This table

Use of the facility public-address system should be limited to use by plant protection personnel in the event of an emergency A True B False

The activity coefficient of the solute is related to its fugacity by Eq (1 187), which may be written:

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