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Lykken (2002) makes an argument for the heritability of negative personality traits, noting that when one member of a pair of identical twins divorces, the chance that the other twin will do so as well is extremely high Trait hostility is also reliably linked to poor relational functioning, especially for men; men s hostility likewise influences their female partner s emotional health (Kiecolt-Glaser & Newton, 2001) Watson, Hubbard, and Wiese (2000) examined associations between the Big Five personality traits (neuroticism, extraversion, openness, agreeableness, conscientiousness), positive and negative affectivity, and marital satisfaction As predicted, people high in positivity rate their relationships as more satisfying and those high in negativity rate their relationships as much less satisfying Extraversion, agreeableness, and conscientiousness were also reliable predictors of satisfaction; neuroticism was associated with dissatisfaction, and openness was unrelated to marital quality.



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tials is subject to errors of * 5 mV, the reliability of the data in Table 82 is fairly high Moreover, because the BCr+/BCr system is used as a solvent-independent potential reference, the potential data referred to it can be compared to some extent even when the data are obtained in different solvents The solvation of metal ions is closely related to solvent basicity (Section 221) Gutmann and his co-workers measured half-wave potentials of various metal ions using the BCr+/BCr reference system and plotted them against the solvent donor number (DN), which was proposed by them as the scale of solvent basicity [20] Figure 84 shows some examples of such relations For all metal ions in the figure, the half-wave potentials shift in the negative direction with increasing DN.





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When rating their partners, the only reliable indicator of relationship (dis)satisfaction was partner negativity Personality and affectivity explained up to a third of the variance in marital satisfaction scores, indicating that individual personality does make a difference in the extent to which couples are happy The work of Robins, Caspi, and Moffitt (2000) shows similar trends Each individual in the couples they studied contributed independently to relationship outcomes Relational happiness was associated with partner s low negative emotionality for both men and women Women s relational happiness was also predicted by her partner s high positive emotionality and constraint (the tendency to act in a cautious manner and to conform to and endorse social norms) AFFECTIVE PROCESSES More than one researcher has noted that positive affect is curiously understudied in the literature on couples adjustment (Gable & Reis, 2001; Heyman, 2001); however, that is changing.

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These results are reasonable because the DN scale is for the strength of solvents as hard bases and because many of the metal ions act as hard acids and many of the organic solvents act as hard bases As described in Section 412, Gritzner [21] used polarographic half-wave potentials to discriminate metal ions that behave as soft acid or as acid between hard and soft from those that behave as hard acid Gritzner [22] also used the polarographic half-wave potentials referred to the BCr+/BCr to determine the Gibbs energies, enthalpies and entropies of transfer of metal ions In determining the enthalpies and entropies of transfer, they measured the effects of temperature on the half-wave potentials The strength of metal ion solvation affects not only the half-wave potentials but also the rates of electrode reactions of metal ions.

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For the reduction of a given metal ion, the reaction rate tends to decrease with increasing strength of solvation The linear relation in Fig 85 was obtained for the reduction of a sodium ion; DG0 (Na+) is the solvation energy of Na+ and ks is the standard rate constant at sv the formal potential [23 a] 2) For alkali metal ions in the same solvent, the rate.

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