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Terms Related to Secondary Bonding Force acting between nonbonded atoms or molecules. Includes the following forces: dipole dipole, dipole induced dipole, and London forces. A dipole dipole force based on electrostatic attraction between oppositely charged poles of two or more dipoles. Measure of the degree of polarity of a polar molecule. Dipole moment is a vector with magnitude equal to charge separation times the distance between the centers of positive and negative charges. Chemists point the vector from the positive to the negative pole; physicists point it the opposite way. Dipole moments are often expressed in units called debyes. Relatively strong dipole dipole force between molecules X H . . . Y, where X and Y are small electronegative atoms (usually F, N, or O) and . . . denotes the hydrogen bond. Hydrogen bonds are responsible for the unique properties of water, and they loosely pin biological polymers like proteins and DNA into their characteristic shapes. Attraction or repulsion between molecules. Intermolecular forces are much weaker than chemical bonds. Hydrogen bonds, dipole dipole interactions, and London forces are examples of intermolecular forces. Intermolecular attractive force that arises from a cooperative oscillation of electron clouds on a collection of molecules at close range. These forces (also known as transitory forces) arise when electron clouds oscillate in step on two molecules at close range. Bond vibrations in molecules may produce the oscillations or they may be triggered by random, instantaneous pile-ups of electrons in atoms.



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4.7. LATERAL SHEARING INTERFEROMETERS USING LASERS As we pointed out earlier, any white-light compensated lateral shearing interferometer works with a laser source. It is possible to devise interferometers that are simpler in constructions and use when requirement for use with white light is eliminated. The most convenient (and cost-effective) laser is the helium neon (He Ne) laser emitting a few milliwatts of power at the 632.8 nm line. A plane parallel plate, devised by Murty (1964a), is undoubtedly one of the most elegant and simplest lateral shearing interferometers for qualitative work in a laboratory. Figure 4.32 shows that the coherent laser radiation is focused by a microscope objective on a pinhole to clean up the beam. The lens (group) under test, having the same f-number as the microscope objective, collimates the divergent light beam. It is incident on an inclined plane parallel plate, normally used without any coating on either surface. The light is re ected from the front and the back of the plate due to Fresnel re ections. The plate thickness introduces the beam displacement, that is, a lateral shear. The lateral displacement S for a plate of thickness t, refractive index N, and for the beam angle of incidence i is given by Malacara (1965a). S sin 2i N 2 sin2 i t 4:30





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Used in optical transmission systems: reshape, reamplify, retime Condition that refers to the fact that the refractive index of a crystal depends on the direction of the electric eld in the propagating light beam Hence, the velocity of light in a crystal depends on the direction of propagation and on the state of its polarization (ie, the direction of the electric eld) The outcome is that (except along certain special directions) any unpolarized light ray entering an optically anisotropic crystal breaks into two di erent rays with di erent phase velocities and polarizations Contrast with optically isotropic, where the refractive index is the same in all directions Examples of optically isotropic materials are most noncrystalline materials (eg, glasses, liquids) and all cubic crystals For all other classes of crystals (excluding cubic structures), the refractive index depends on the propagation direction and the state of polarization.

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When one views an image through an optically anisotropic crystal, one sees two images, each constituted by light of di erent polarization passing through the crystal Optical multiplexing device that uses interference e ects between di erent waveguides of progressively longer optical path length on a planar substrate (typically silicon) The interference e ect directs each wavelength (typically arriving on di erent ports on the AWG) onto an output port that is coupled to a ber output Range of frequencies where propagating modes of a signal or wave are absent This also is applicable to optics In a semiconductor material, the minimum energy necessary for an electron to transfer from the valence band into the conduction band, where it moves more freely [255].

Bragg angle ( ) is de ned by the expression 2d sin n , where is the angle between a crystal plane and the di racted X-ray beam; is the wavelength of the X-rays, d is the crystal plane spacing, and n is the di raction order (any integer) The Bragg law is the cornerstone of X-ray di raction analysis because it allows one to make accurate quanti cation of the results of experiments carried out to determine crystal structure It was formulated in 1912 by W L Bragg in order to explain the observed phenomenon that crystals only re ect X-rays at certain angles of incidence [256].

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