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It is not reasonable to expect that the 2p orbital of a methyl group will have approximately the same energy as the 2p orbital of a tri uoromethyl group (assuming it were planar) Because of the strong inductive e ect of the electronegative uorine atoms acting in the s framework, the carbon atom of tri uoromethyl would be signi cantly denuded of electrons The 2p orbital is in e ect more electronegative and falls below Can one deduce reasonable values for the e ective electronegativity of the p orbitals of C upon reduction of the coordination number from 3 to 2 (ie.



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, C2), as in alkynes, allenes, nitriles (R CN), or carbenes, or even to 1, as in CO, isonitriles (R NC), or acetylides A linear extrapolation from dicoordinated O O2 2X09j j and dicoordinated N N2 0X51j j to dicoordinated C yields an estimate of the energy of the 2p orbital as 0X86j j This value is probably too high It places the energy of the 2p orbital of a dicoordinated carbon above that of the 2p of a tricoordinated boron, but the same is not true in the case of a dicoordinated N and a tricoordinated C, and the.

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Decision-feedback equalization and identi cation of linear channels using blind algorithms of the Bussgang type In 29-th Asilomar Conference Signals, Systems, Comp, pages 335 340 vol1 IEEE, 1996 943 CB Papadias and A Paulraj A space-time constant modulus algorithm for SDMA systems In Proc IEEE VTC, pages 86 90 vol1, Atlanta, GA, 1996 944 CB Papadias and A Paulraj Space-time signal processing for wireless communications : a survey In First Signal Processing Workshop on Signal Processing Advances in Wireless Communications SPAWC 97 , Paris, France, pages 285 288, April 16-18 1997 945 CB Papadias and AJ Paulraj A constant modulus algorithm for multi-user signal separation in presence of delay spread using antenna arrays IEEE Signal Processing Letters, 4, No 6:178 181, June 1997 946 CB Papadias and DTM Slock New adaptive blind equalization algorithms for constant modulus constellations.

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and analyzed this quest for the ultimate goal in high solids in a study titled The Slow and Winding Road to Zero VOC It is concluded that zero VOC would be possible from liquid coatings if we could use cured coatings that have a very low glass transition temperature, for example a Tg around room temperature or below Such coatings would be soft and/ or rubbery, of course For suf cient hardness, automotive coatings of the acrylic melamine type are designed to have values of Tg between 50 and 100 C It is also pointed out [14] that zero solvent content does not always mean zero VOC If the binder molecular weight is decreased drastically, then compounds in the low end of the molecular weight distribution are quite volatile and may be lost from the coating during cure.

In International Conference on Acoustics, Speech and Signal Processing (ICASSP-94)Adelaide, Australia, pages III 321 324, April 19-22 1994 947 CB Papadias and DTM Slock Towards globally convergent blind equalization of constantmodulus signals: a bilinear approach In Signal Processing VIII: Proc EUSIPCO-94, 1994 948 CB Papadias and DTM Slock Normalized sliding window constant modulus and decisiondirected algorithms: a link between blind equalization and classical adaptive ltering IEEE Trans Signal Processing, 45(1):231 235, January 1997 949 A Papoulis Probability, Random Variables, and Stochastic Processes McGraw-Hill, NJ, 1991 950 Y Park, KM Park, I Song, and H-M Kim Blind channel identi cation and equalization from second-order statistics and absolute mean IEICE Trans Communications, E79B(9):1271 1277, September 1996 951 TW Parsons Separation of speech from interfering speech by means of harmonic selection Journal of the Acoustical Society of America, 60(4):911 918, Oct 1976 952 A.

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