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The scenarios described here do not necessarily present the most ef cient possible outcome. Ideally your customers know exactly what they need and give you their full cooperation while spelling out the requirements in crystal-clear detail. Things don t always go that way, however (in fact, I ve never seen it happen that way), so neither do the steps described here. Perhaps you ll get lucky and things will go more smoothly than some of the discussions described here, but you should realize that at least sometimes people skills are as important as database design skills during this phase.



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1.2. Intermediate precision (interrun precision)

User view (1) ERD(1)

Figure 15-32: A Basic dimension. Use the Vertical Position drop-down list to determine how the tolerances are aligned with the main dimension text. This setting has the greatest effect on Deviation tolerances that display two lines of text for the one dimension text line. You have the following choices: Top: Aligns the tolerance text with the top of the dimension text. Middle: Aligns the tolerance text with the middle of the dimension text. Bottom: Aligns the tolerance text with the bottom of the dimension text.





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2. Use an orbital interaction diagram to explain the observation that tetracyanoethylene is very easily reduced to its radical anion. 3. The highly strained ole n, spiropentadiene, has been synthesized (Billups, W. E.; Haley, M. M., J. Am. Chem. Soc., 1991, 113, 5084) after more than a decade of theoretical investigations which predicted signi cant spiroconjugation. Discuss the p bonding of this compound. Answer. The high symmetry of spiropentadiene D2d limits the possibilities for interaction of orbitals of one ring with orbitals of the other. Thus the p bonding orbital of one ring cannot interact by symmetry with either the p or p orbitals of the other ring. Only the p orbitals of the two rings can interact, but as both are unoccupied, no stabilization ensues from this interaction. However, a plausible interaction which may lead to extra stabilization is the interaction of the occupied p orbital of one ring with the unoccupied Walsh orbital of the other, as shown below, leading to two two-electron, two-orbital stabilizations, a form of homoconjugation.

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Both ground-based and satellite measurements have unambiguously established that the stratospheric ozone concentrations have been slowly falling since the mid1980s (see Appendix B for a discussion of Stratospheric Ozone Depletion) The ozone concentrations in the stratosphere are latitude dependent and the decline in concentrations is uneven The Antarctic winter ozone hole (with about a 50% loss in ozone within it) in the 1990s is an extreme case of the depletion exacerbated by the polar meteorological features A similar seasonal loss has been seen in the Arctic as well In midlatitudes (25 N to 60 N) average total ozone was lower by 4 6% in the 1990s compared to 1980 While meteorological factors also contribute to the phenomenon of stratospheric ozone loss in midlatitudes, this depletion is believed to be mainly related to halogen-catalyzed photochemical destruction of ozone in the stratosphere.

The data from the method validation data should be analyzed as the data are obtained and processed to ensure a smooth ow of information. If an experimental error is detected, it should be resolved as soon as possible to reduce any impact it may have on later experiments. Analysis of the data includes visual examination of the numerical values of the data and chromatograms followed by statistical treatment of the data if required.

The emission of CFCs into the atmosphere is believed to be primarily responsible for the occurrence of atmospheric chlorine CFCs were used as physical blowing agents in the production of polyurethane and polystyrene foams used in building insulation applications and in aerosol spray cans The excellent thermal insulation properties of the gas and its non ammability made it a good candidate for these purposes These gases diffuse out of the foam and into the environment over the years of product use or once the foam is destroyed CFCs persist long enough in the environment37 to reach the stratosphere and once there interfere with the photochemical reactions responsible for maintaining the ozone layer (see Appendix B on Ozone Layer Depletion) The loss of stratospheric ozone directly affects the UV-B content of terrestrial sunlight The increase in the terrestrial UV-B (290 315 nm) radiation has far-reaching effects on the biosphere.

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