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As shown in Fig. 4.7, the thermodynamic potential window of water depends on pH but its width is * 1.23 V, irrespective of the pH of the solution. If the entire width of the potential window of water is estimated by the positive potential limit at pH = 0 and the negative potential limit at pH = 14, it is * 2.06 (= 1.23 + 14 0.059) V. For non-aqueous solvents, it is rare that the thermodynamic potential windows are definitely determined. For most amphiprotic solvents (SH), the negative ends of the potential windows are determined by their reductions, which generate molecular hydrogen and the corresponding lyate ions (S ): 2SH 2e 3 H2 2S 2 For alcohols (ROH) and acetic acid, they are as follows: 2ROH 2e 3 H2 2RO 2 2CH3 COOH 2e 3 H2 2CH3 COO 2 However, their oxidation processes are often complicated and it is not easy to define the positive ends of the potential windows thermodynamically. In aprotic solvents, both the reduction and oxidation processes of solvents are complicated and definite estimation of thermodynamic potential windows is almost impossible. For these reasons, it is usual to determine practical potential windows voltammetrically, using appropriate indicator electrodes. A voltammogram is measured in a solvent under study, in the presence of an electro-inactive supporting electrolyte. The negative end of the potential window is where the reduction current begins to flow, while the positive end is where the oxidation current begins to flow. However, in order that the reduction and oxidation of solvents can occur at the

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In organizations with successful downsizing efforts, senior leadership understood and conveyed to employees a direct correlation between efficiently managing the downsizing process and maintaining the viability of the organization Surviving employees perceive the fallout from a downsizing as potentially threatening to their careers, and this perception forces many often the very talent a downsized organization can least afford to lose to consider other job opportunities 2 Too much communication is impossible What employees want most, the report found, is open and honest communication from leadership about what is happening during downsizing The open and honest attributes of communication also imply that management will listen to employees as well as vice versa Employees want news and information even bad news to come from the top during downsizing.

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constraint placed on retrieval speeds if the le (typically a movie) is stored only on one disk. One way round this is to synchronise a number of disks and stripe the data across them, sector by sector (Figure 4.17). The multiple disk array can be treated as providing a set of logical disk sectors each of which is n times larger than that of a single disk (where n is number of disks involved). Thus the transfer rate is increased n times also. Where long les of movies, for example, have to be stored and are likely to be accessed at independent random times, the above method has problems with buffering. In this scenario, a better solution may be to interleave successive blocks of each movie across successive sectors on different disks (Figure 4.18). This arrangement permits a number of alternatives for data retrieval, which can be designed for load optimisation [35].

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88 Base Technologies atoms as in an EDFA In particular, a wide variety of usable semiconductor materials are available And, by placing two facing mirrors around the region of the material in which stimulated emission is occurring, one can create a source of radiation, a laser, by having any stray optical waves at any of the many resonant frequencies of the cavity formed by the two mirrors become repeatedly reinforced by a cascade of many successive stimulated emission events But how is the stimulated emission produced The answer is shown in Figure 314 (the P I curve) With zero pump signal, the medium is essentially opaque, but as the pump intensity increases, a state of transparency is reached at which there are frequent enough random spontaneous transitions of the electrons from higher to lower energy levels (Fig 3.

Explaining the business reasons for the downsizing repeatedly and consistently helps prevent feelings of unfairness and promotes the sentiment that the downsizing is a shared experience Town hall-style meetings are particularly effective, the study found, as were employee information hotlines, more frequent newsletters, and frequent allstaff meetings One organization in the study found that employees wanted information weekly or biweekly during the downsizing process Information not normally required in an organization s day-to-day operations becomes critical during downsizing For example, management requires information for planning and monitoring the staff reduction, and employees need information to help them decide on a course of action.

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