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In these cases, to achieve acceptable resolution in these small regions, uniform resolution methods will result in a very ne discretization of the entire domain Consequently, it requires a signi cant amount of unnecessary computation and storage Instead of using uniform discretization or re nement to obtain ner resolution, SAMR techniques dynamically apply nonuniform re nement on different regions according to their local resolution requirements SAMR techniques track regions in the domain, which require additional resolution and dynamically overlay ner grids over these regions This technique concentrates computational efforts ( ner grids with ner integration time steps) on regions that exhibit higher numerical errors These methods start with a base coarse grid with minimum acceptable resolution that covers the entire computational domain As the solution progresses, regions in the domain requiring additional resolution are tagged and ner grids are overlaid on these tagged regions of the coarse grid.



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Re nement proceeds recursively so that regions on the ner grid requiring more resolution are similarly tagged and even ner grids are overlaid on these regions The resulting grid structure for the structured Berger Oliger AMR is a dynamic adaptive grid hierarchy [3], as shown in Figure 121..

The Express Tools command BURST (choose Express Blocks Explode Attributes to Text) converts attributes to text. Apply the ATTOUT and ATTIN commands (choose Express Blocks Export). Attribute Information and Import Attribute Information work together to enable you to edit attributes in another program. For example, ATTOUT creates a tab-delimited file that you can open in Notepad or Excel. When you use ATTIN, existing blocks are updated with the new attribute information.





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bond if base attack is at the C H bond Operation of the E2 mechanism therefore has a very strong stereoelectronic requirement that the C H and C X bonds be able to achieve a (nearly) coplanar arrangement In terms of the intrinsic stabilization, there is not much di erence between the syn coplanar and anti coplanar arrangements The observation that the E2 reaction proceeds predominantly by anti elimination is easily explained on steric grounds The anti arrangement of two bonds at adjacent tetracoordinated centers corresponds to a minimum in the potential function for rotation about the single bond, whereas the syn (or eclipsed) arrangements corresponds to a maximum.

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rectangles, while the sign structures belonging to the semiotic world are drawn as rounded rectangles. This gure also shows that activities are performed as a result of task performance of an actor. A plan may be one of the programs that are relevant for the task performance. Because plans generally underspecify what must be done, the actor has to use additional programs resulting from his personal knowledge. 5.2.4. Multi-actor Simulation Models Multi-actor theory is based on the idea that a system that shows complex behavior has to generate this behavior by performing computations. We see the behavior of such a system for instance, an organization or society as complex because that behavior cannot be described by traditional mathematical tools for instance, mathematical equations (Wolfram, 2002, p. 3). The shortcut taken by traditional mathematics will only work when the behavior of the system is simple. In the case of complex behavior, this behavior can more often than not be simulated by computations that use the interaction of computer agents following simple rules. This is the basic idea behind computational mathematics (Holland, 1995, 1998; Wolfram, 2002). The complex behavior at the system level of description can be seen as emergent relative to the simple rules represented at the agent level of description (Holland, 1998). This discovery has led to a new form of theory development based on the principle of computational equivalence. Computational equivalence means that whenever one sees behavior that is not obviously simple . . . it can be thought of as corresponding to a computation of equivalent sophistication (Wolfram, 2002, p. 5). Because of the

In cyclic systems, where adjacent C H and C X bonds are forced into syn coplanar arrangements by ring constraints, the E2 elimination still proceeds, albeit at a reduced e ciency probably due to steric shielding of the C H bond by the adjacent halogen The gas-phase E2 reaction of CH3 CH2 Cl with F and PH2 (proton a nities 1554 and 1552 kJ/mol) has been investigated by high-level ab initio computations [234] With F as the nucleophile, a small di erence of 4 kJ/mol was found, favoring the SN 2 pathway over the E2 (anti) pathway However, the E2 (anti) pathway was preferred over the E2 (syn) route by 53 kJ/mol Fluoride was predicted to be considerably more reactive than PH2 , for which relative transition state energies of 00, 49, and 84 kJ/mol were found for the SN 2, E2 (anti), and E2 (syn) transition states, respectively.

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