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27 Feb 2019 ... We've rounded up the very best PDF editors which will cost you nothing at all. ... to view and print documents without requiring the original software that ... Don't bother downloading the Windows app: it essentially replicates ... (a) Sketch the highest occupied molecular orbital (HOMO) and the lowest unoccupied molecular orbital (LUMO) on the basis of the calculation. (b) Assuming that 5 (R H) were to react with an electrophile, where is the most likely site of attack Compare the Lewis basicity of 5 (R H) to that of ethylene. (c) Assuming that 5 (R H) were to react with a nucleophile, where is the most likely site of attack Compare the Lewis acidity of 5 (R H) to that of ethylene. (d) In terms of j j, estimate the energy of the lowest p p electronic excitation of 5 (R H). Is it plausible that compounds with this structure might be colored Explain in three lines or less. (e) Calculate the p bond order of the C1 C2 bond of 5 (R H). (f ) Calculate the net charge of atom C1 of 5 (R H). (g) Choose a suitable reagent and show the most likely product in a reaction between it and fulvene, 5 (R H). 6. Use principles of orbital interaction theory to explain the lower Lewis acidity of the allyl cation, [CH2 CHCH2 ] , compared to the methyl cation, [CH3 ] . Answer. The Lewis acidity depends on the interaction energy heL from the interaction of the LUMO of the acid with the HOMO of the nucleophile. The interaction is of s type, with the base HOMO (usually a nonbonded p or sp n hybrid) interacting end on with the LUMO, which for the methyl cation is a single 2p orbital and for the allyl system is a linear combination of 2p orbitals. The LUMOs of the two systems are shown below. pdf editor for windows 10 online List of PDF software - Wikipedia
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