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32. Click the Close button at the upper-right corner of the AutoCAD application window to close both AutoCAD and the drawing.



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Free PDF Editor is a free piece of software for editing and customizing PDF files. It is a simple piece of software that can be used to create PDF files from scratch ...

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Answer to 4(d). This question asks us to explain a structural change, pyramidal to planar, that distinguishes the tricoordinated nitrogen atom of amides from amines in general. Stuctural changes may ensue from a minimization of repulsive interactions (four-electron, two-orbital) and/or maximization of attractive interactions (twoelectron, two-orbital). The latter is almost always the case, although question 3(c) dealt with an exception. We therefore adopt a two-electron, two-orbital interaction diagram where the ``interacting'' fragment orbitals are the LUMO of the carbonyl group and the occupied valence orbital of a neighboring tricoordinated nitrogen. Since one of the interacting orbitals (the carbonyl group orbital) is a complex orbital, the interaction will be treated as coming entirely from the orbitals of the two atoms closest to each other, the N and the C. According to general principles, the LUMO of the C O group is the pCO , which is polarized toward C (the less electronegative end), and so should interact strongly with the single orbital of N. This is p if the nitrogen is planar and sp n if it is pyramidal. The two situations are depicted in Figures B3.5a and B3.5b. The interaction is more favorable if the overlap is maximized. The p-type overlap is maximized if the two orbitals are both p orbitals with their axes parallel (Figure B3.5b). As a consequence, the nitrogen becomes planar and the plane of the NH2 group coincides with the plane of the carbonyl group. The preceding discussion is su cient to answer the question of nitrogen planarity. Many other properties of the amide group can be explained on the basis of the same diagram. The amide group is discussed in greater detail in 8 and a more general interaction diagram is provided there (Figure 8.6a).

many vertices, so it s not important that you find the exact one.) 6. Type m to move the vertex. At the Specify new location for marked vertex: prompt, pick a point slightly above the existing vertex. Then type x to exit the Edit vertex submenu. 7. At the main PEDIT prompt, type s . PEDIT smoothes out the polyline. 8. Press Enter to exit the PEDIT command. 9. Save your drawing.

The best use of the MText option is to add some text before or after the measurement, such as TYP typical used when one dimension applies to several objects) or subject to final approval. To add text before the measurement, simply start typing. To add text after the measurement, press the End or Right Arrow key and then type. To replace the existing text, click the text to select it and enter the replacement text. Then click OK to close the In-Place Text Editor.

Figure 17-7

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