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SUSJECT INDEX Hamiltonian formulation, 22.33, 61, 214 Hamiltonian operator, 426 Hamiltonian vector field, 424425 Heat, 9,401 Heat bath method. see Monte Car10 siinulations Heat capacity, 59, 199 Heat conduction, 31,49,265 anisotropic, 75 Heat flux, 48, SO, 60.63.68 atomistic expression, 3 18 elementary kinetic theory, 267 from Chapman-Enskogexpansion, 296 from Grad s moment method, 301 kinetic theory, 3 18 Heaviside step function, 131 Heisenberg picture, see Quantum mechanics Heisenberg uncertainty principle, see Quantum mechanics Helmholtz free energy, 22, 29, 344,405,409 configurational, 118, 121 conformation-tensordependence, 122,344 energetic and entropic contributions simulation results, 349 from cumulant expansion, 345 gradient of, 118 Helmholtz potential minimum principle, 406 Hermite polynomials, 299 properties of, 300 Hilbert s theory, see Boltzmann s equation Hilbert space, 421,457 Holonomic constraints, see Constraints Homogeneous flows, 49,122 polymer solutions, 127-128 steady, 122 Hookean springs, see Entropic potential Hopf bifurcation, 22 Hubble parameter, 192-193 H theorem, see Boltzmann s equation Hydrodynamics check of Jacobi identity, 65 criticism of conventional formulation,44.61 decomposition of friction matrix, 68 with diffusion, 69 derivation of, 33 diffusion, 6 2 4 3 discrete formulation of, 69 equations, 50,60 equations from Chapman-Enskog expansion, 289 equations from Grad s moment method, 303 fluctuations, 2 7 , 5 9 4 0 forces and fluxes, 74 friction matrix, 57.61.68 limit of rapid relaxation, 164 local nature, 52 nonlinearity of equations, 50





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Until the late 1990s, the chondrogenic assays for mammalian progenitor cells isolated from postnatal tissues consisted of various methods for implantation of the cells in vivo, generally in scaffolds or diffusion chambers [Brown et al., 1985; Cassiede et al., 1996; Goshima et al., 1991; Harada et al., 1988; Jaroma and Ritsila, 1988; Nakahara et al., 1990]. The implants were then harvested and submitted for histologic evaluation of the tissues formed. This implantation method has been used for proof of concept studies of chondrocytes in various scaffold types [Cao et al., 1997; Isogai et al., 1999; Paige et al., 1996; Sims et al., 1996]. However, although it can be used for assessing the differentiation potential of cells, it is limited for tissue engineering with chondroprogenitor cells. Thus the development of in vitro systems for inducing chondrogenesis was important. A method based on the pellet culture system that was rst used for the culture of differentiated chondrocytes was developed [Johnstone et al., 1998; Yoo et al., 1998]. Pellet culture was rst described by Holtzer et al. [1960] for culturing chondrocytes in conditions that maintained their differentiated phenotype. It was later adapted for use with growth plate chondrocytes and allowed the study of the differentiation of proliferative chondrocytes into the hypertrophic state [Ballock et al., 1993; Chen et al., 1995; Inoue et al., 1990; Iwamoto et al., 1991; Kato et al., 1988].

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