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In Fig. 13.18, the normalized current ratio of Brij 56 templated TSUAmodi ed nanocomposite lms is B40%. However, in another experiment using P123-templated lms that have a larger pore size (ca. 6.5 nm), the normalized current ratio is only B1.2%. Because the molecular length of azobenzene ligands located on the pore surfaces is B1.8 and 1.5 nm in the trans and cis forms, respectively, the optically triggered restriction in pore size is expected to have a diminished effect on transport for P123-templated lms compared with the smaller pore size Brij 56 templated lms. As described earlier, azobenzene-functionalized nanoporous silica lms exhibit dynamic photocontrol of their pore size, which in turn enables photoregulation of mass transport through the lm. Their potential applications in nano uidic devices, nanovalves, nanogates, smart gas masks, membrane separation, and controlled release can be anticipated. 13.3.3.3. Effective Diffusion Coef cient of Ferrocenedimethanol in the Nanopores. To evaluate the effective diffusion coef cient of FDM in the azobenzene-modi ed nanocomposite lms, the chronoamperometry experiments were performed as a function of the concentration of the FDM probe. At low concentrations of FDM, the oxidative current reached the steady state within 2 min, whereas high concentrations of FDM took longer to stabilize. The steadystate current at 10 min was chosen to evaluate the effective diffusion coef cient. On the basis of Fick s and Faraday s laws for diffusion-limited current, the following formula was used to estimate the effective diffusivity of probe molecules in the nanoporous membranes. I nFADeff C H



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This statement places a border around the window menu. The characters used to draw the border are specified: | for the vertical lines, - for the horizontal lines, and + for the four corners.

1 2 3 4 5 6 7 8 #include <ncurses.h> int main(void) { WINDOW *newman; initscr(); start_color();





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where n is the number of electrons involved in the electrode reaction; in this case, n = 1; F is the Faraday constant, 96485 C/mol; D is the effective diffusion coef cient; A is the O-ring (7/16 in. in diameter) area exposed to the buffer solution; C is the concentration of FDM in the nanocomposite lm; H is the lm thickness. As shown in Fig. 13.19, the steady-state current vs. the concentration of FDM curve is not linear. It tends to saturate at high concentrations of FDM. However, in the dilute solution region, it is linear. The slopes of the two curves without UV exposure are 5.9 10 4 A/M and 4.1 10 4A/M, respectively. The effective diffusion coef cients (Deff) of the FDM probing molecules across the photoresponsive nanocomposite lm under UV light irradiation and room light exposure are estimated to be 1.6 10 10 cm2 s 1 and 1.1 10 10 cm2 s 1, respectively. These values are comparable with that of the transport of rohdamine 6G dye (8 10 11 cm2 s 1) in the mesoporous PNIPAM-modi ed silica particles at 501C as reported by Lopez and colleagues recently (Fu et al., 2003). These values are much smaller than the diffusion of free molecules in solution (B10 5 cm2 s 1). However, they are reasonable because the tortuous nature of the nanoporous lm greatly reduces the diffusion coef cient.

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CORBA Technology Projection Thread pooling. This standardizes the support and configuration of thread pools by ORBs. Introducing new features to the existing and widely-used CORBA API is a problem. How can the ORB be extended with RT-CORBA features without changing the CORBA::ORB API The solution is to use the Extension Interface pattern [SSRB00], which allows transitioning between interfaces of the same component. This allows components to be extended with additional interfaces while retaining existing interfaces: lookup of extended interfaces is done via a special operation. The aforementioned resolve_initial_references on the CORBA::ORB interface is used to obtain a reference to the RTCORBA::RTORB extension, implementing the Extension Interface. Thus, non-real-time ORBs and applications are not affected by RT-CORBA extensions.

9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27

4.0 3.5 3.0 Current ( A) 2.5 2.0 1.5 1.0 0.5 0.0 0 2 4 6 8 Concentration of FDM (mM) 10 12

init_pair(1,COLOR_YELLOW,COLOR_RED); newman = newwin(5,30,5,10); if( newman == NULL) { endwin(); puts( Error creating window ); return(1); } wbkgd(newman,COLOR_PAIR(1)); wborder(newman,0,0,0,0,0,0,0,0); mvwaddstr(newman,1,1, Ta-da! ); wrefresh(newman); wgetch(newman); endwin(); return 0; }

CORBA::ORB_var orb = CORBA::ORB_init (argc, argv); CORBA::Object_var obj = orb->resolve_initial_references ("RTORB"); RTCORBA::RTORB_var rtorb = RTCORBA::RTORB::_narrow (obj);

Sample output: The program creates a window on the screen 30 characters wide by 5 characters tall. The window is colored red with yellow text. A border is drawn around the window, and text inside the border says Ta-da!.

Figure 13.19. Plot of the steady-state current vs. concentration of FDM. Circles represent the current measured under UV exposure whereas rectangles represent the current measured under room light exposure.

14, Appendix B, box(), hline(), vline()

box()

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