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A group can also be used as a mask, as long as it consists of filled shapes and as long as the mask doesn t also include simple ungrouped shapes: If a mask is composed of multiple items, using a group usually facilitates positioning the mask, as shown in Figure 10-16.



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This book contains many examples, and the workbooks for those examples are available on the companion CD-ROM, arranged in directories that correspond to the chapters. Refer to Appendix B for a complete list of the files. In addition, the CD-ROM contains an electronic version of this book. It s a searchable PDF file that s a perfect companion for your notebook computer when you take your next cross-country flight.

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Benzoic Acid The industrial-scale oxidation of toluene to benzoic acid is carried out with cobalt catalysts 973 ,978,982,983 The process, a free-radical autoxidation, is significantly promoted by bromide ions 984 Under these conditions bromine atoms rather than alkylperoxy radicals serve as a regenerable source of chain-initiating free radicals Substantial rate increase can be achieved by the addition of manganese(II) ions 984 Liquid-phase oxidation of toluene to benzoic acid (Dow process,980,985,986 MidCentury process987 ) may be carried out in acetic acid or without solvent Cobalt(II) naphthenate or cobalt(ll) 2-ethylhexanoate promoted by bromine is used as the catalyst at 140-190 C, at about 8-10 atm pressure The highly exothermic oxidation is run until about 50% conversion In a process developed by SNIA Viscosa,988,989 Co(ll) heptanoate or Co(OAch in water is used Benzaldehyde is always the major byproduct Terephthalic Acid The oxidation of p-xylene to terephthalic acid is a more difficult reaction.

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866 Once one of the methyl groups is oxidized, the second methyl group in p-toluic acid formed is deactivated by the electron-withdrawing effect of the carboxylic group Bromine-promoted catalytic processes and cooxidation in the presence of suitable additives are usually practiced 97o,978,99o The Mid-Century-Amoco process 987 employs a mixture of Co(OAch and Mn(OAc h as the catalyst and bromine compound cocatalysts (NH4Br and tetrabromoethane) in acetic acid solvent Since terephthalic acid is not soluble in acetic acid it crystallizes in high purity during oxidation (220 C, about 20 atm) The oxidation is run to almost complete conversion with better than 90% selectivity Certain organic compounds, when cooxidized together with p-xylene, promote the formation of terephthalic acid These promoters, such as acetaldehyde (Eastman-Kodak process991 ), paraldehyde (Toray process992 ), and 2-butanone (Mobil process993 ,994), supply oxygen-containing radicals which regenerate the Co (III) catalyst.

When you place long or complex calculation expressions into a custom function, you can use a single custom function name in your calculations in place of a much more convoluted expression. For an expression used only once in your solution, there may be little value in replacing it with a custom function because the complexity of the code is simply moved from the calculation definition to the custom function definition. However, if your solution references the expression in multiple places, defining its logic as a custom function provides a number of benefits. The first and most obvious benefit of placing a complex calculation into a custom function is that it makes coding easier throughout the various occurrences of the logic in your solution. An added benefit is that if you need to update the logic of the calculation, a single update (to the custom function definition) propagates throughout your solution.

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