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The structure of 1,3-difluoropropane has been investigated by Klaboe et al. (1982). IR spectra were obtained of the compound as a vapor, in solution, and of the unannealed and annealed solid between 4000 and 30 cm I . Raman spectra were recorded of the liquid and of the unannealed and the annealed solid. The authors show that in the vapor phase the compound exists in at least three conformations. The ratios of the conformational abundance are given in brackets GG(63), AG(27) and GG"( 10). The dominant GG conformer is the one which persists in the crystalline state, too. Durig and Little ( 1981) determined the conformational barriers to internal rotation of methyl vinyl ketone by IR and Raman spectroscopy. They recorded IR spectra of the gaseous and the solid states and the Raman spectrum of the liquid state. They also determined the potential function for internal rotation of the asymmetric top and obtained the following potential constants: V1 = 180 f 9, V 2 = 827 f 107, V3 = 113 I 8, and V4 = 150 5 34 cm I. According to these data, the s-ti-uns conformer is the predominant form at ambient temperature, and the enthalpy difference between the s-ti~ansand the s-cis conformer in the gas phase is 280 cm I. The relative intensities of the Raman bands as a function of the temperature afford an enthalpy difference of 172 cm for the liquid.

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8.4.1.6 What Is the Advantage of lntracellular Phosphorolysis Versus Hydrolysis of Glycogen Phosphorolysis is particularly advantageous for skeletal muscle and heart, which utilize the glucose units of glycogen for energy within the cell. As discussed in 4, phosphorylation of sugars serves both to activate them and to trap them within the cell. Mobilization of glycogen by phosphorolysis thus ensures that the exercising muscle can utilize the glycogen-derived glucose for its energy needs directly rather than allowing that glucose to be released into the bloodstream. Another advantage of phosphorolytic degradation of glycogen as opposed to hydrolysis of glycogen is that generation of glucose phosphate instead of free glucose permits the glycogen-derived glucose to bypass the initial activation step of glycolysis: the hexokinase or glucokinase reaction. As also discussed in 4, each glucose molecule entering the glycolytic pathway requires 2 ATP to produce the activated glycolytic intermediate, fructose 1,6-bisphosphate. Subsequent glycol ysis to lactate generates 4 ATP, for a net yield of 2 ATP/glucose. Phosphorolysis of glycogen, in effect, conserves some of the activation energy required for glycogen synthesis and only requires the input of one ATP to generate fructose 1,6-bisphosphate. This

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Frequency bands (F, GHz) e/s off-axis e.i.r.p. (dBW) e.i.r.p. ( ) 32 25log( )(*) 39 25log( )(**) 32 25log( )(***) NOTES:

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The DCME is a baseband equipment which processes the trunks switched by the telephone exchange (eg the international switching centre (ISC)) This is why it should very often be installed in the telephone exchange premises, with the echo suppressors/cancellers and the various signalling facilities Moreover, locating the DCME at the telephone exchange and a CSF in the earth station allows the benefit of circuit multiplication to be also obtained on the exchange-to-earth station microwave link This is one advantage of selecting the multiclique mode for multiple destinations operation of the DCME In consequence, users with one or two destinations per DCME could select the multiclique mode, and place the DCMEs at the exchange Users with a smaller amount of traffic per destination (and with more than two destinations) could select the multidestination option.

TABLE 16.1 1996 U.S. Radioactive Waste Inventory Type/Origin Military HLW LLW SNF (MTHM)a TRU Mill tailings Commercial HLW LLW SNF (MTIHM)a Mill tailings

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Three typical examples of DCME and earth station equipment configurations (which can be either new and complete earth stations, or retrofitted units used for equipping existing stations with digital/DCME communications) are given in the following figures: Figure 88 shows a simple configuration for implementing a 2 Mbit/s FDMA-TDM-PSK/DCME link with two destinations in the multiclique mode The equipment consists of three subsystems: the RF and converters subsystem (antenna, LNA, HPA, U/C and D/C) In the usual case where the two received carriers are transmitted through the same satellite transponder, a common down converter can be used; the "signal processing terminal" which comprises the modulator and two demodulators (with, if required, forward error correction encoders/decoders) and the transmit (Tx) and receive (Rx) baseband modules In these modules are included various baseband digital functions, such as buffering, framing, scrambling/descrambling, engineering service channels addition/extraction, etc.

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