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Practical Applications Acid-catalyzed oligomerizations are practiced industriallyI4-17 Isobutylene dimerization is a very important process It yields diisobutylene, mainly a 4: 1 mixture of 2,4,4-trimethyl-l-pentene and 2,4,4-trimethyl2_pentene,18,19 which may be catalytically hydrogenated to 2,2,4-trimethylpentane (isooctane) The reaction can be carried out with sulfuric acid The so-called hotacid process (68% H2S04, 80 C)20 has the advantage over the cold-acid method that in addition to dimerization of isobutylene, codimerization of isobutylene and n-butylenes also occurs In this way higher dimer yields (87-90%) are achieved An acidic ion-exchange resin at 100 C and about 20 atm (Bayer process)17 yields dimers and trimers formed in a ratio of 3 : 1 at almost complete conversion Oligomer distribution can be affected by temperature; increasing temperature brings about a decrease in molecular weight.



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If the CAS server s database indicates that the user has the appropriate privileges, the CAS issues the user a GSI restricted proxy credential with an embedded policy giving the user the right to perform the requested actions 5) The user then uses the credentials from the CAS to connect to the resource with any normal Globus tool (eg GridFTP) The resource then applies its local policy to determine the amount of access granted to the community and further restricts that access based on the policy in the CAS credentials This serves to limit the user s privileges to the intersection of those granted by the CAS to the user and those granted by the resource provider to the community 76 Resource Manager for Globus-based Wide-area Cluster Computing, Tanaka, Y, Sato, M, Hirano, M, Nakada, H and Sekiguchi, S.





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Inferno's graphics system is described in more detail in the manual pages draw-intro(2), tk(2), image(6) and font(6) [79]. There are many texts that provide an introduction to interactive computer graphics, such as [17, 21, 73]. Inferno's graphics system will be evolving to something along the lines of the current graphics model in the Plan 9 operating system. The theoretical foundation for this is provided in [57]. A good reference text on Tk is [48]. Inferno's Tk implementation is described in [32]. Cellular automata or cellular arrays (C As) were first proposed by John von Neumann [46]. John Conway's Game of Life [4], is one of the most popular CA rules. Norm Margolus and Tommaso Toffoli have built hardware CA machines, which are described in [35, 78]. The ancestors of the game Pong are games developed by Ralph H. Baer circa 1966 [3, 67] and Nolan Bushnell (of Atari) [8].

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Solid or liquid phosphoric acid is used in industry to produce gasoline polymers from Cr C4 alkenes I-23 The most prevalent is UOP's solid phosphoric acid catalyst Also called silicophosphoric acid, it is a pelletized calcined mixture of H3P04 and kieselguhr 1 This catalyst was widely used in the oligomerization of propylene, a once important large-scale industrial process to produce propylene trimer and tetramer 15,16 Oligomerization can be accomplished at 170-220 C and 14-42 atm The once-through tetramer yield is relatively low ("-J 20%), but the dimer and trimer are recycled to attain high overall yields Both the trimer and tetramer were used to alkylate benzene in the production of detergents Their use, however, has diminished because of the poor biodegradability of the product branched alkylbenzenesulfonate.

A solid acid catalyst introduced in 1985 is used in UOP's Hexall process to selectively dimerize propylene at high conversion 4 The C6 olefin content of the product can reach higher than 90% with an octane number of 95-96 Oligomerization promoted by H-ZSM-5 is a crucial step in the Mobil olefinto-distillate-and-gasoline process 5 When operated at relatively low temperature and high pressure (200-300 C, 20-105 atm), called the distillate process, the products are higher-molecular-weight isoolefins 6,27 Under these conditions light olefins are first converted to higher oligomers Subsequent isomerization and cracking give intermediate C4-C7 olefins Finally the latter participate in copolymerization to yield the product The high selectivity of the process (selective formation of higher isoolefins) is a result of the shape-selective action of ZSM-5 preventing hydrogen transfer reactions 8 The retardation of conjunct polymerization (formation of polyunsaturated and aromatic compounds) ensures long catalyst life.

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