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Since 1984, the NMIs and the national accreditation bodies (NAB) have been collaborating in order to allow the free movement of calibration documents The process of securing the traceability to the SI system is made simpler for industries.



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There are many other influencing quantities: the hygrometric level of air, electric and magnetic fields, shocks and vibrations and, it must be added, the location of the instruments in the area, which act as an influencing parameter A measuring instrument should reach the accuracy stated by its manufacturer after a period of stabilization, when it is motionless, sitting on a horizontal surface, at the rated temperature often +20 C plugged in on the 50Hz mains at precisely 220V, or if it is battery operated, when the batteries are new What happened the accuracy when these conditions change In other words, how do influencing quantities interact And how does one become free of them This is a difficult problem because of the frequent lack of information in technical notices.





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The Beer Lambert law tells us that a plot of absorbance against concentration should be linear with a gradient of l and will pass through the origin. In theory, to analyse a solution of unknown concentration, solutions of known concentration need to be prepared, a suitable band chosen, the absorbance at this wavenumber measured, and a calibration graph plotted. The concentration o the compound in solution can be read from the calibration graph, given that its absorbance is known. There are a few factors which need to be considered when taking this approach. First, the preparation of solutions of known concentrations: these concentrations have to give sensible absorbance values not too weak and not too intense. There is also the choice of a suitable absorption peak: this technique needs to be as sensitive as possible and so an intense peak should be chosen. However, often infrared spectra have many, sometimes overlapping peaks. A peak isolated from others, with a high molar absorptivity, should be found. A further problem that sometimes arises, especially in the spectra of solid samples, is the presence of asymmetric bands. In such cases, peak height cannot be used because the baseline will vary from sample to sample and peak area measurements must be used instead. FTIR spectrometers have accompanying software that can carry out these calculations (calibration methods are introduced below in Section 3.9). Quantitative measurements need to be carried out on absorbance spectra. Thus, transmittance spectra need to be converted to absorbance spectra. The determination of the concentration of a gas needs to be considered separately from solids and liquids [5]. The ideal gas law relates the physical properties of a gas to its concentration. This law states that: P V = nRT (3.6)

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We suggest that you make a list of the criteria to consider when choosing an instrument, then to attribute to each criterion a coefficient depending on how important each criterion appears to be, and then a mark The items on this grid should come from the analysis of the criteria undertaken by the manager of the metrological activities (the person in charge of the metrological function in the firm), the user, the buyer and the personnel responsible for the maintenance Each person s opinion will thus be taken into account The important thing is to make a careful list of questions and provide an answer to each one It is true that experience is not easy to weigh, but the object of this method is just to provide a starting point to work out a decision (Table 12)..

It can be solved by making a list of the influencing quantities, finding their effects in order to get rid of them or compensate for them, or even assess their effects As an example let us take the case of metal gauges that dilate when the temperature rises It will be necessary: to assess the interference of the influencing temperature quantity: this may entail finding out about the alloy of the gauges in order to know their dilatation coefficient; to get rid of the influencing quantity, which still in the same case will imply a reduction of the variations of temperature affecting the references and elements being controlled; to proceed by compensation: this will be possible if the element to be measured has the same dilatation coefficient as the gauges.

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