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arrangements that are possible for metal ions along the polymer chain Di erent types of supermolecular associations can be formed (eg, metal ions can either be separately arranged along the chain or they can form dimers, trimers, multiplets, block structures and ionic clusters (Section III) If the ions weakly interact with the polymer, phase separation occurs and ionic clusters are formed In other words, in addition to the units that include the metal atoms, the polymers can also contain ionic domains that have no metal nor separate fragments of metal ions that are clustered We will present here only the most representative examples For example, the ESR spectrum of the V4 ions that are formed on polymerization of V5 -containing monomers is broadened due to exchange interactions and give rise to a broad singlet.



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87 Such a polymer can be regarded as a cooperative system in which the V4 ions are included in the matrix of the V5 ions In all probability, the associated species are formed around the vanadium atoms that crosslink two polymer chains This may increase the probability that other vanadium atoms will aggregate The absorption spectra of styrene copolymers with metal-containing vinylporphyrin monomers is a superposition of the spectra of porphyrin units that are located close together and do not interact126 The di erences in the chain conformations that are caused by the addition of porphyrin units through a pyrrole ring have been demonstrated by spectroscopy127 A typical example of ionic clusters is the structure of lithium sorbate (C6H7LiO2), which consists of separated organic and inorganic layers In this twodimensional (2D) network structure, lithium ions are located at both corners and at the edges of the lattice.





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Why Greatness the process of clearing away the fog so that the island can be seen clearly for what it is The greatest coaches reveal their clients to themselves ARGUMENT 2: NOT EVERYBODY CAN BE GREAT Someone has to clean the toilets, right There s not enough to go around Some people win, some people lose These are all common expressions of scarcity mentality Inherent in this argument is the assumption that there is not enough to go around and that it s not possible for everyone to live his or her ideal life This is a model based on scarcity and competition I can succeed only if someone else fails My failure equals someone else s success I can t be an astronaut, so I m not that great This argument de nes greatness in hierarchical terms That is, if you re great, I m not, and if I m great, you re not Greatness is unique to each individual No one can de ne it for another How you de ne greatness will differ from everyone you meet More precisely, your greatness is uniquely yours Everyone is great in his or her very own unique way It s what makes life so richly diverse and ensures that everyone can live into his or her inherent capabilities Your job is to help your coachee rediscover his or her own de nition, shaking off the illusions that were put in place by parents, teachers, friends, family, and society Sure, not everyone will become president of a country Not everyone will become a famous actor who becomes president of a country Your coachee may not walk on the moon or save the world from itself But your coachee can, and dare I say it should fully express his unique greatness as a gift back to the world into which he was born a uniquely gifted and talented individual For any of us to deprive the world of who we are is a sel sh, cynical act To do what we can do and be the person that we are is the purest act of love The world can t live without it It is this very questioning of worth that keeps so many people from doing what they can do They can t imagine being president, or some other lofty goal, and suddenly any goal they do have pales in comparison The underlying assumption here is that anything of value has to be larger than life Go big or go home And yet, on further inspection, we nd that it is really the little things done consistently that bring greatness As Mother Teresa said, We can do no great things; only small things with great love After spending two years as a VISTA volunteer working with the poor and homeless, I learned an amazing lesson I quickly realized I wasn t going to eradicate poverty But what I could do was make a difference one 33.

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128 During polymerization, the orientation of these monomeric units is retained, at least, partially In Cu2 and Fe3 polyacrylates, exchange interactions occur, which may be due to the speci c binuclear and trinuclear structure of these MCMs89 The composition diagrams of styrene copolymers with cobalt or nickel acrylate point to the tendency for the formation of alternating copolymers129 that is, alternating structures account for 42% of the total number of acrylate groups (calculated from the constants for relative reactivities of the comonomers) In addition, metal ions can be remote from one another Hence Ti4 -Ni2 metal copolymers are ensembles of noninteracting (or even discrete, in regard to electron localization) sites, although they are linked by the polymer chain (scheme 29)130.

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