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The SAR of dibenzocyclooctadiene lignans and related biphenyl derivatives can be summarized as follows: (1) The biphenyl feature is needed for anti-HIV activity in dibenzocyclooctadiene lignans. A C-6b benzoyl group, C-7a hydroxy substituent, and methylenedioxy substitutions on the aromatic rings are important for enhanced anti-HIV activity. 7b-Hydroxylation or bromination on the biphenyl skeleton diminishes the activity. (2) In the case of Bz substituted hexahydroxy-biphenyl derivatives, the two hydroxymethyl groups at C-2 and C-20 seem to be essential for speci c HIV inhibition. (3) When the hexahydroxybiphenyl skeleton is substituted with methylenedioxy and methoxy groups, 3-bromination on one or both phenyls greatly increased the anti-HIV activity. C-2 methoxycarbonyl groups on both phenyls and the position of the methylenedioxy and methoxy groups are essential for the anti-HIV activity. Methoxy at C-4 and methylenedioxy at C-5,6 of each phenyl produced the best activity. 9.3.4 Mechanism of Action of Biphenyl Derivatives

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The made-control circuit changes the converter's mode of operation from PWM to Hysteretic and visa versa, based an the voltage polarity of the SW node when the lower MOSFET is conducting and just before the upper MOSFET turns on. For continuous inductor current, the SW node is negatlve when the lower MOSFET is conducting and the converters operate in fixed-frequency PWM mode as shown in Figure 10 This mode of operation achieves high efficiency at nominal load. When the load current decreases to the paint where the inductor current flaws through the lower MOSFET in the 'reverse' direction, the SW node becomes positive, and the mode is changed to hysteretic, which achieves higher effciency at law currents by decreasing the effective switching frequency. To prevent accidental mode change or "mode chatter" the transition from PWM to Hysteretic mode occurs when the SW node is positive for eight consecutive clock cycles (see Figure 10) The polarity of the SW node is sampled at the end of the lower MOSFET's conduction time. At the transition between PWM and hysteretic mode both the upper and lower MOSFETs are turned off. The phase node will 'ring' based on the output inductor and the parasitic capacitance on the phase node and settle out at the value of the output voltage.

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Heme is also the prosthetic group for a large class of hemoproteins called cytochromes. Whereas the iron in hemoglobin and myoglobin remains in the ferrous (Fe2+) state as molecular oxygen is bound successively to and then released from the molecule, the iron in cytochromes accepts and donates electrons by undergoing reversible interconversion between the ferrous (Fe2', reduced) and ferric (Fe+3,oxidized) forms. Heme-containing enzymes include prostaglandin H synthase (a.k.a. cyclooxygenase), and catalase, which converts hydrogen peroxide to water and 0 2 . Heme is also a component of members of the superfamily of cytochrome P450xontaining enzymes that catalyze the oxidation of many molecules, including steroids and xenobiotics. Cytochromes differ from each other in the nature of the side chains attached to the porphyrin ring. Furthermore, in some cytochromes, such as cytochrome ci, the porphyrin ring is covalently bound to the protein through the side chains of two cysteine residues of the protein via thioether bonds with vinyl groups of protoporphyrin IV.

These dimensionless numbers can also be combined. For example, the ratio DaR/DaD compares the dissolution rate to the reactor throughput while the product DaRNNu compares the nucleation rate with the reactor throughput. The exact form of the dimensionless numbers would change as the reaction kinetics, the growth rate expressions, etc. change, but the meanings would remain the same.

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