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Compared to the measurement of VCD the measurement of optical activity in the Raman spectrum offers all the well known advantages that Raman spectroscopy has over infrared spectroscopy: the use of the inexpensive glass as the sample cell, and the occurance of fewer bands, overtones and combination bands are reduced in intensity, thereby diminishing the possibility of overlap. Very important also is the fact that water is usable as solvent. The first genuine ROA effects were measured by Barron et al. in 1973, following some earlier claims which proved to be artifacts. Two years later, the first review of Raman optical activity (and on Rayleigh OA) by Barron and Buckingham (1975) appeared. The theory of ROA is explained in the book of Barron (1982), which also detailes other types of optical activity. The measurement of optical activity in Raman spectra is most often done by measuring the circular intensity difference (CID) and the circular intensity sum (CIS). Using this technique the linearly polarized laser beam used for excitation is modulated with a KD*P electrooptical modulator resulting in an excitating beam which changes its state of polarization from left to right circularly polarized at a frequency of about 1/3 Hz. The Raman intensities are then collected separately and the dimensionless Raman CID calculated using: (6.3-22) Here ZR and IL are the Raman intensities measured with right and left circularly polarized excitation light, respectively. As there could be some confusion between the circular intensity difference and the dimensionless circular intensity difference (which is only occasionally given in the literature), the latter should be given a different name, e.g. DCID.



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Figure 15.2 Average channel capacity per unit bandwidth for a Rayleigh fading and an AWGN channel versus average SNR (with no diversity).





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ager might overweight a segment in anticipation of a narrowing of spreads, which will lead to an increase in return over that of the benchmark. We calculate the asset allocation effect to capture the return differential due to yield spread changes and other segment allocation factors. The asset allocation effect is calculated by comparing the segment benchmark excess return to the total benchmark excess return, weighted by the relative weight of the fund and benchmark in each segment. For example, in our fund we overweighted corporates, and the benchmark corporate segment had a higher corporate excess return than the benchmark average excess return, leading to 0.063% of value added due to asset allocation to corporates. The security selection effect is calculated by comparing the fund and benchmark segment excess returns, weighted by the fund weight (here we incorporate the interaction effect into the selection effect). We earned a small security selection effect in corporates by achieving a higher excess return than the benchmark excess return in that segment. We can interpret the security selection effect as the value added due to selecting bonds that perform better than the average bond within the corresponding index segment. For example, if we successfully select bonds that we believe will receive an upgraded credit rating, we would pick up excess return relative to the benchmark because a higher credit rating leads to a lower required yield, increasing the bond s return. EXHIBIT 19.13

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1. Open the Design Form dialog box (shown earlier in Figure 26.1). 2. Open the Look In list at the top of the dialog box and select the folder where you originally published the form. 3. Select the form from the list. 4. Click Open.

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disc[y4] = (tr[^l]) - 4\A\ are the trace, determinant and discriminant of the two dimensional matrix [A].

K = 0 (Rayleigh)

> 0; n = 1, 2, . . .

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The fdisk utility is available with most every Linux system for creating and working with disk partitions in Linux. It does the same job as graphical partitioning tools such as Disk Druid, although it s no longer offered as an option during Fedora installation. However, during Fedora installation, and other Linux installations that have virtual terminals running, you can switch to a shell (press Ctrl+Alt+F2) and use fdisk manually to partition your hard disk. The following procedures are performed from the command line as root user.

There are more than 2500 different enzymes in the human body. It is useful to group them into six major classes based on the type of reaction they catalyze.

Coordination of the metabolic activities of different organs serves to support glucose homeostasis and provide a steady supply of glucose to meet the needs of the brain and erythrocytes, both of which are constantly dependent on glucose as fuel. Integrated metabolism also serves to store fuel efficiently in times of plenty in order to provide for periods of fuel scarcity or times of high energy utilization.

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