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and properties of polymers. As applied to metal-containing polymers, the concept can be further developed and substantially enriched because the composition and structure of metal-containing groups can vary over wide limits. Metal-containing polymers can be produced by all the known methods that are used to synthesize highmolecular-weight compounds namely, most often radical polymerization63,64 or less often polycondensation of the corresponding monomers.65 Polymerization and copolymerization of MCMs are of interest for the preparation of structurally homogeneous products with speci ed properties.66 The main problem in this route is the synthesis of the corresponding monomers. Depending on the nature of the linkage between the metal of valency n and the ligands containing a multiple bond, MCMs can be classi ed into several types, which are presented in Table 5.67,68 In the general case, MCMs are metal complexes with speci c ligands whose most important property is the ability to polymerize.69 In these monomers, metals do not act as chain-forming centers (i.e., they are not included in the backbone), but serve as peculiar pendant groups. The reactivities of MCMs di er markedly; some polymerize even during their synthesis, whereas others are unable to polymerize or polymerize only with di culty even under fairly drastic conditions (high temperature, pressure, and concentration of an initiator or catalyst). The limitations imposed on the polymerization of most known MCMs are associated with their solubility, possible dissociation and change in their composition in solution. When analyzing polymerization of MCMs, it is reasonable to assume that the composition of the polymer formed corresponds to that of the initial monomer. In reality, this is not always true. In the formation of these polymers, some units appear

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INTRODUCTION Transmission control protocol/IP (TCP/IP) has become a de facto platform for most of the computer systems in the world. Besides that, it is a common well-known fact that IP has to be somehow adjusted to work adequately with multimedia and other general applications, becoming very popular in networks, including the Internet and other TCP/IP networks. QoS provisioning to application and end users in IP networks then becomes the challenging task for network designers, managers, researchers and, generically, technical staff. The objective of this chapter is to elaborate on this subject by presenting an introductory overview of the main technical solutions available for QoS in IP networks. We will first elaborate on the importance of this field and then review the most important solutions and propositions for QoS provisioning in IP networks. The plan of the chapter is as follows: Section 3.1, IP Context and Quality of Service, introduces the importance of the field, identifies the overall perspectives and makes an attempt to foresee IP evolution. Section 3.2, Quality of Service, examines some common basic principles for QoS, presents a taxonomy for applications, and introduces the most important basic parameters frequently used to characterize, analyze, and manage QoS requirements. Section 3.3, Quality of Service: Approaches and Initiatives for IP Networks, summarizes the main approaches used to control and manage QoS and presents some additional basic concepts.

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