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As outlined in Sec 3613, both stimulated Raman gain spectroscopy (SRGS) and inverse Raman spectroscopy (IRS) or stimulated Raman loss spectroscopy (SRLS) fall into the class of coherent nonlinear Raman techniques SRGS and IRS differ only in that spectra are obtained in the former case by using a Stokes shifted probe laser to scan the gain profile produced by a pump laser source, whereas in the latter case of IRS, an anti-Stokes shifted probe laser is used to scan the absorption profile (loss) on the opposite side of the spectrum relative to the pump frequency (Jones and Stoicheff, 1964; Owyoung et al, 1978; Owyoung, 1981) Thus, scanning of the frequency of one of the laser sources relative to the other results in a direct display of the Raman spectrum.



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The only difference in respect to the spontaneous Raman spectrum will be that, since this is a stimulated process, the signal will scale as the difference in population between the upper and lower level rather than being directly proportional to the lower-level population The advantages of SRGS and IRS are that the signal (in contrast to CARS) is linearly proportional to the spontaneous Raman scattering cross section (and to the product of the two laser intensities), and that the phase-matching condition is automatically fulfilled and there is no nonresonant background As already mentioned in Sec 3613 the resolution of the nonlinear Raman techniques is limited only by the laser linewidths These qualities give the stimulated Raman techniques particular appeal under conditions where interference from background luminescence is problematic or in situations where very high resolution is required.

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The main disadvantage of these techniques, however, is that they are quite sensitive to laser noise The latter requires high stability in laser power Pioneering work on stimulated Raman spectroscopies was performed using pulsed high-power laser sources in order to induce appreciable Raman gain or loss that could be easily observed (Jones and Stoicheff, 1964) Later techniques employed stable cw lasers and detect the small ( w changes in intensity due to Raman gain or loss (Owyoung et al, 1978; Owyoung, 1979 and 1981) Due to complexity only a few stimulated Raman gain and loss spectrometers with main application in high resolution molecular spectroscopy have been built since the fundamental developments by Owyoung et al in 1978.

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An important improvement has been the realization of the quasi-cw stimulated spectrometer (Owyoung, 1979), wherein a single-[node stable cw laser provides a low-noise probe source and a high-power repetitively pulsed laser system provides the pump source Such a scheme is diagrammatically shown in Fig 36-14 for inverse Raman (Raman loss) spectroscopy (Owyoung, 1979)..

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