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De ning the star schema enables fast OLAP queries against the warehouse, but gaining needed consistency requires following some warehousing rules: When loading data into the warehouse, null and invalid values should be replaced with their reportable equivalents. This enables the data s semantics to be researched carefully once and

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The physical interfaces must comply with common standards (V.11, V.24, X.21 and HDB3, ) depending on the data rate. The ESC functions provide operation such as insertion/extraction of the dedicated channel into/from the normal traffic channel. Synchronous multiplexing of overload bits for the provision of ESCs and alarms is also accomplished in the framing unit. The clock of the data transmission along the satellite link may be provided by a network clock, a local earth station clock, or from the incoming signal. A plesiochronous buffer copes with asynchronism, jitter and doppler effects. The last function of the framing unit is to give some minimal stochastic characteristics to the data stream sent to the link. The two main purposes are scrambling for energy dispersion of the transmitted spectrum and of the receiver synchronization, and interleaving that permits spreading out bursts of errors generated by loss of synchronization in decoders. This latter technical approach is also used in the implementation of Reed-Solomon codes.

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It is possible to develop all the tools and procedures to accomplish all of these tasks, but it can be a tedious and potentially risky endeavour. Some of the backup applications offer a vaulting option that is fully integrated with the backup solution, which is much easier to use and more reliable. Figure 1.2 shows the basic vaulting process ow. There are at least three options for creating a backup image that will be taken off-site for secure storage:

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Exceptions seem to be handled inconsistently. Indeed, the semantics are not very well defined in the SOAP standard. In the structure of a SOAP message, there is a SOAPFault section. This seems to be reserved for exceptions. In Axis, RemoteExceptions are indeed marshaled through the SOAPFault section. However, application-level exceptions pretty much anything that s not a RemoteException are marshaled as <wsdl:exception> elements within the response. Unfortunately, the semantics of an exception still vary from one SOAP implementation to another. In an interoperability scenario, this can cause problems in detailed exception management. On the plus side, the notification of an exception can still be relied on.

Conjugation with other unsaturated groups shifts the v(C=C) frequency to lower values, as, for instance, in the spectrum of acrylonitrile (Fig. 4.1 -4A). Conjugation of several C=C groups results in just as many coupled C=C vibrations, which - depending on the symmetry and on the spatial arrangement - may be IR and/or Raman active. Model calculations have demonstrated that the position of the in-phase and the out-of phase C=C vibration in a diene exhibit a characteristic dependence on the dihedral angle (Fig. 4.1-5) (Schrader and Ansmann, 1975). The in-phase C=C vibration in an s-trans diene, showing a strong Raman band, is observed at a higher frequency (isoprene, 2chloro-l,3-butadiene, Figs. 4.1 -4B and C) than the out-of-phase vibration, which shows a strong infrared band. In the case of s-cis dienes (1,3-cyclohexadiene, Fig. 4.1-6A), the strong band in the Raman spectrum, the in-phase vibration is found at a lower frequency than the nut-of-phase vibration, which is represented by a somewhat stronger IR band. These facts are useful for the elucidation of the structure of sterically hindered C=C-C=C systems in chains or rings. A similar coupling may be observed for a , / -unsaturated aldehydes and ketones. Table 4.1-3 shows that the s-cis or s-trans conformation of the C=C-C=O systems is indicated by the difference of the frequencies of the C=O and the C=C stretching vibration as well as by its relative intensity in the infrared and the Raman spectrum and the depolarization factor in the Raman spectrum (Oelichmann et al., 1982).

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