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crystallization, the PDHS lm exhibits a strong in-plane optical anisotropy (Fukuda et al., 2002a,b; Seki et al., 1999). The polarized absorption spectra show that the Si backbone is highly aligned perpendicular to the polarization plane of the actinic light. The aligned direction of the PDHS main chain agrees with that of the Az orientation on the substrate. The crystallization of the PDHS chain occurs on the photooriented Az monolayer in an epitaxial manner. The atomic force microscopic (AFM) observation reveals that ne brous structure is evolved along the polarization direction. Most probably, PDHS chains form an edge-on lamella on the photooriented 6Az10-PVA monolayer. The main chains of PDHS are folded orthogonal to the polarization plane of LPL, and thus the resultant bers are evolved parallel to it (Fig. 8.1, left) (Seki, 2007).



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chtype termattrs(void); attr_t term_attrs(void);

The functions return a long int bit field with bits set according to which attributes the terminal is capable of producing. The chtype attributes are defined in NCURSES.H and are prefixed with A; attr_t attributes are also defined in NCURSES.H and prefixed by WA.

De ned-sized mesoporous metal oxide materials are synthesized by templating organic molecular assemblies (Kresge et al., 1992; Yanagisawa et al., 1990). The templating rodlike micelles form lyotropic LC states, and therefore, the hexagonally packed rods are oriented by the structural anisotropy of the surface. The photoorientation of an Az monolayer is transferred to a photooriented spincast lm of a polysilane as the rst step (Seki et al., 1999), and then deposition of mesoporous silica lm is performed (Kawashima et al., 2004, 2002). In this attempt, the photoorientation of the Az monolayer is rst transferred to a

25.09.2004 21:11





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It s possible to ferret out specific attributes by using a logical OR with the attribute constant and the value returned by termattrs(). The attr_get() function is used to read attributes currently being used in a window. See attr_get(). Refer to Appendix C for more information on the chtype attribute constants.

printw( The terminals attributes value is %X.\n ,termattrs());

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photooriented spincast lm of PDHS as mentioned earlier, and then oriented deposition of surfactant silica hybrid lm is performed (Fig. 8.2, left). The formation of uniaxially aligned mesochannels is con rmed by transmission electron microscopy (TEM) for the photoaligning layer of 6Az10-PVA PDHS. The two TEM photographs in Fig. 8.3 depict the cross-sectional structure of the as-synthesized surfactant silica hybrid lm observed in the two directions orthogonal to each other. Figure 8.3a shows the image when the lm is sliced parallel to the direction of the actinic polarized light. The hexagonal structure of the mesochannels is clearly visualized through the overall thickness of the lm. However, when the lm is sliced perpendicular to the direction of the actinic polarized light, the lines with a periodicity of 3 4 nm running parallel to the substrate are observed (Fig. 8.3b). The periodic length coincides well with that of the hexagonal spacing obtained by X-ray diffraction (XRD). The cylindrical structure of the mesochannels is fully stretched straight in the lm. Figure 8.3b shows the heterointerface regions composed of the Si wafer (the dark region at the bottom), Az monolayer (2 nm thickness, not clearly shown), PDHS lm (40 60 nm thickness, brighter region), and deposited mesochannels with parallel stripes. The orientational information possessed by the Az monolayer (almost invisible in the photograph) is transferred to the alignment of PDHS with a thickness of ca. 50 nm and then to the mesostructured channels with a thickness of ca. 400 500 nm. Thus, large ampli cations with respect to the controlled mass amounts are attained. An alternative simpler way is to use a photocross-linkable LC polymer lm containing a cinnamoyl unit and a mesogen in the side chain developed by

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