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interference shielding for military applications and radar absorption SWNT-based materials represent the future aerospace vehicle construction material of choice based on predicted strength-to-weight advantages and inherent multifunctionality [182] SWNT-based composites are still in their infancy Nanoparticles can be incorporated into polymeric coatings to facilitate measurable improvements in targeted properties, for example, scratch resistance, UV resistance, conductivity, and the like Commercial-grade processing methods have been developed in the recent past to control the average particle size and particle size distribution of the dispersed nanoparticles; these integrated technologies allow transparent coatings containing nanoparticles to be formed in a plethora of resin formulations [183].



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If it s important to have text data representing numbers sort in the proper order, you might want to pre x the numerals with zeros (001, 002, etc.). Then the text values will sort in the expected order: 001, 002, 003, 004, 005, 010, 100. n FIGURE 34-16





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As pure carbon molecules, SWNTs o er a wide variety of derivatives for compatibilizing, dispersing, and coupling with a host polymer; furthermore, SWNTs can be considered a new type of polymer because the molecules can be modi ed chemically and regarded as a backbone polymer the basis of new classes of block-andgraft copolymers [89] Nanotubes are especially promising for biomedical applications because one is able to tailor them for speci c parts of the body For example, nanotubes that assemble themselves using the same chemistry as DNA may be used for creating better arti cial joints and other body implants Researchers have discovered that the self-assembling nanotubes represent an entirely new and potentially superior material to use for arti cial body parts [184, 185] Bone cells (osteoblasts) attach better to nanotubecoated titanium (Ti) than they do to conventional titanium used to make arti cial joints.

FIGURE 18-9

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Bone cells and cells from other parts of the body attach better to various materials that possess surface bumps about as wide as 100 nm; conventional titanium used in arti cial joints has surface features on the scale of microns, causing the body to recognize them as foreign and prompting a rejection response Helical rosette nanotubes (HRN) are a new class of self-assembled organic nanotubes possessing biologically inspired nanoscale dimensions Because of their chemical and structural similarity with naturally occurring nanostructured constituent components in bone such as collagen and hydroxyapatite, researchers believe that an HRN-coated surface may simulate an environment that bone cells are accustomed to interacting with [184, 185] Other applications envisioned include the following [2]: solar cells in roo ng tiles and siding that provide electricity for homes and facilities; this can result in a much cleaner environment due to greater use of solar energy.

Prototype tires exist today that provide improved skid resistance, reduced abrasion, and resulting longer wear, although a date for market introduction had not been announced as of press time The nanocomposites being used in tires can be used in other consumer products such as high-performance footwear, exercise equipment, and car parts (belts, wiper blades, and seals) (Nanocomposites, not just SWNT-based nanocomposites are discussed further in a subsection that follows) New commercial applications of nanotechnology that are expected within 5 years in the pharmaceutical and chemical industries include advanced drug delivery systems (eg, implantable devices that automatically administer drugs and sense drug levels) and medical diagnostic tools, such as cancer tagging mechanisms Finally, some researchers also contemplate nanoscale machines comprised of gears built with nanotubes and close variants, as illustrated in Figure 410..

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23However,the value of y cannot be reduced at will by the designer. As we are going to see, its value needs to meet certain existence conditions (see, e.g., (45.15)).

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Objectives After completing this chapter you should be familiar with:

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