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This means that immediately after pulse irradiation, a nonequilibrium state is produced, which is thermodynamically an isotropic phase in its equilibrium state but shows an anisotropy because orientational relaxation of mesogens is not completed The response of the whole LC systems depends strongly on this orientational relaxation of the mesogens, which in fact is the rate-determining step, especially in highly viscous LC polymers that require a relatively long time (Ikeda, 2003) A new system has been developed in which every mesogen in the LC or LC polymer is photosensitive (Ikeda, 2001; Tsutsumi et al, 1998b; Tsutsumi et al, 1997; Ikeda and Tsutsumi, 1995) For example, the azobenzene moiety could play roles as both a mesogen and a photosensitive moiety (Fig 320) in azobenzene derivatives that form LC phases.



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Appendix C, inch(), addchstr()

init_color()

These azobenzene LCs show a stable LC phase only when the azobenzene moiety is in the trans form, but do not show an LC phase when all the azobenzene moieties are in the cis form Examination of these azobenzene LCs revealed that a nematic isotropic phase transition is induced in the azobenzene LC polymers within 200 ns over a wide temperature range under optimized conditions (Ikeda, 2001)..

The init_color() function allows you to redefine colors NCurses can use for text attributes. For those terminals on which this function works, you can create interesting colors by adjusting individual red, green, and blue values, theoretically creating a billion possible colors.





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int init_color(short color, short r, short g, short b);

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Even in monophasic systems, polymer properties can be bene cial to photoresponses and can level up the effects beyond the association dissociation occurring at the molecular scale. Intrapolymer associations of colloid nanoparticles (e.g., micelles or proteins) most typically exhibit multipoint attachments, that is, several azobenzene groups would simultaneously attach onto the same particle. Chemical equilibrium requires that the energy of transfer of azobenzene from water into their binding sites balances the conformation energy of the chain segments forming loops on the particle (Fig. 7.5a). In addition, if a necklace of bound colloid particles is formed, an additional intrachain particle particle interaction may also contribute to the association energy. Finally, at concentration above C* for the polymer, the association may transiently cross-link the chains and markedly modify the dynamic and mechanical properties. Altogether, these contributions to association result in complex responses to photovariations of the af nity for azobenzene. This section presents the essential features of such

c is a short int representing a color number to change. The range of valid values for c is from 0 through the value of COLOR. (See COLOR.) r, g, and b are short int values representing the intensity of the red, green and blue hues of the color created. Values range from 0 through 1000, where 0 is black and 1000 is full intensity for red, green, or blue.

24.09.2004 20:59

Use the can_change_color() function to determine whether or not the terminal has the ability to redefine its colors set. When can_change_color() returns TRUE, then the init_color() function can be used.

Bound nanoparticle (protein, micelle, vesicle, etc) (b)

When all three color arguments, red, green, and blue, are set to the same value the result is a gray tone. The lower the value, the darker the gray; the higher the value, the lighter the gray. The default colors used by NCurses relate to the init_color() statements shown in Table A-7. The color_content() function is used to determine the red, green, and blue color values of colors in NCurses, kind of the opposite of the init_color() function. See color_content() elsewhere in this appendix.

Figure 7.5. Schematic drawing of the light-responsive association between a exible polymer and nanoparticles. See color insert.

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