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Subsequently, photoinduced birefringence and surface relief structures have been reported in a photosensitive supramolecular material obtained by the ISA of poly(1-ethylvinylpyridinium bromide) and of commercially available azobenzene dye Methyl Orange (Xiao et al, 2007), as shown in Fig 210 However, a different mechanism of relief formation reported by the authors has to be stressed here The complex has a rigid molecular structure because of the absence of a spacer between the main chain and azobenzene unit and exhibits a lamellar organization with a periodicity of 27 nm Within this lamellar self-assembly, the disordered polyelectrolyte soft segments were alternated by the stacking of the Methyl Orange rigid side chain Laser-induced periodic surface structures (LIPSS) have been formed upon irradiation with an s-polarized beam of a pulsed UV laser operating at the wavelength of 355 nm if the intensity was high enough.



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The period of the relief structure was strongly dependent on the incident angle of the laser beam At a period of about 400 nm, a relief depth of 100 nm was attained Formation of LIPSS was considered to be a result of thermal-induced macroscopic mass movement of molecules The high thermal stability of the induced.

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http://www.opengroup.org/products/publications/catalog/tp.htm [Ped04] The Pedagogical Patterns Project, 2004 http://www.pedagogicalpatterns.org [PS97] H. Peine and T. Stolpmann: The Architecture of the Ara Platform for Mobile Agents, Proceedings of the First International Workshop on Mobile Agents, Volume 1219, Lecture Notes in Computer Science, pages 50 61, Springer-Verlag, Berlin, Germany, April 1997 R. Pawlak, L. Seinturier, L. Duchien, G. Florin: JAC: A Flexible Framework for AOP in Java, in Reflection 2001: Meta-level Architectures and Separation of Crosscutting Concerns, pages 1 24, Kyoto, Japan, Sep 2001 M. Quinn: Parallel Programming in C with MPI and OpenMP, McGrawHill, 2003 I. Rammer: Advanced .NET Remoting, APress, 2002 D. Riehle: Bureaucracy, in Pattern Languages of Program Design 3, Eds. R. Martin, D. Riehle, F. Buschmann, Addison-Wesley, 1997 E. M. Rogers: Diffusion of Innovations, 4th Edition, Free Press, 1995 Roxio, Inc.: The Napster Homepage, 2004 http://www.napster.com [RSB+97] D. Riehle, W. Siberski, D. B umer, D. Megert, H. Z llighoven: Serializer, in Pattern Languages of Program Design 3, Eds. R. Martin, D. Riehle, F. Buschmann, Addison-Wesley, 1997 T. Saridakis: A System of Patterns for Fault Tolerance, Proceedings of the 7th European Conference on Pattern Languages of Programs (EuroPLoP 2002), Irsee, Germany, July 2002 T. Saridakis: Design Patterns for Fault Containment, Proceedings of the 8th European Conference on Pattern Languages of Programs (EuroPLoP 2003), Irsee, Germany, June 2003

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relief structures up to 1301C is noticeable The complex itself was stable at least up to 2751C The surfaces with LIPSS were used to align liquid crystals It should be commented here that probably the mechanism of LIPSS formation is different from the light-induced mass transport discussed in this chapter The authors investigated neither the induction of relief structures upon modulated irradiation nor the light reversibility of LIPSS, which makes it dif cult to compare these results Recently, the inscription of SRG in a similar dye polyelectrolyte spacer-free ionic complex shown in Fig 210 has been reported (Zhang et al, 2008) Although there is no spacer between the azobenzene unit and polymer chain, the material exhibits liquid crystalline SmA order SRGs with a grating spacing of 1 mm were induced in a 5- to 10-mm thick lm using rather low irradiation intensities of 65 mW/cm2 (Zhang et al.

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, 2008; supporting information) The surface modulation depth approached 200 nm after 225-h irradiation The photoinduced birefringence in this material has been reported to be both temporally and thermally stable, but the authors did not comment on the thermal stability of the induced SRG The polarization dependence of the grating inscription, especially interesting in the case of liquid crystal material, was not commented on either The supramolecular approach would not be complete without the materials based on hydrogen bonds Among intermolecular interactions, the latter is characterized by its directionality and moderate strength (Table 21) It is very interesting to clarify whether the light-driven mass transport demonstrated for ionic complexes of azobenzene is as well effective in the H-bonded supramolecular materials Recently, a main-chain supramolecular azobenzene polymer based on selfcomplementary quadruple hydrogen bonds has been developed (Fig 24e) (Gao et al, 2007b).

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