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a polymer that has an appropriate pendant group (usually a phenyl) (Wang et al., 1997a,b,c). The rst method is preferred for its simplicity and control of sequence distribution. The second takes advantage of commonly available starting materials, but may require more reaction steps. Many different backbones have been used as scaffolds for azo moieties, including imides (Agolini and Gay, 1970), esters (Anderle et al., 1989), urethanes (Furukawa et al., 1967), ethers (Bignozzi et al., 1999), organometallic ferrocene polymers (Liu et al., 1997), dendrimers (Junge and McGrath, 1997; Mekelburger et al., 1993), and even conjugated polydiacetylenes (Sukwattanasinitt et al., 1998), polyacetylenes (Teraguchi and Masuda, 2000), and main-chain azobenzenes (Izumi et al., 2000a,b). The most common azo polymers are acrylates (Morino et al., 1998), methacrylates (Altomare et al., 2001), and isocyanates (Tsutsumi et al., 1996). Thin lms are usually prepared by spincoating (Han and Ichimura, 2001; Blinov et al., 1998; Weh et al., 1998; Ichimura et al., 1996), although there are also many examples of using solvent evaporation, the Langmuir Blodgett technique (Silva et al., 2002; Razna et al., 1999; Jianhua et al., 1998; Seki et al., 1993), and self-assembled monolayers (Evans et al., 1998). Spin-cast lms are typically annealed above the polymer glass transition temperature (Tg) to remove residual solvent and erase any hydrodynamically induced anisotropy. Recently molecular glasses have been investigated as alternatives to amorphous polymer systems (Mallia and Tamaoki, 2003). These monodisperse systems appear to maintain the desirable photomotions and photoswitching properties, while allowing precise control of molecular architecture and thus material properties (Naito and Miura, 1993).



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Table A-6: NCurses functions that affect input FUNCTION ON/OFF cbreak() nocbreak() echo() noecho() halfdelay() intrflush(win,TRUE) intrflush(win,FALSE) keypad(win,TRUE) keypad(win,FALSE) meta(win,TRUE) meta(win,FALSE) nodelay(win,TRUE) nodelay(win,FALSE) notimeout(win,TRUE) notimeout(win,FALSE) raw() noraw() qiflush() noqiflush() timeout(delay) typeahead() DESCRIPTION Disables text input line buffering and erase/kill character processing Controls display (echo) of text as its input Similar to cbreak mode, though with a timeout value Activates text buffer flush on interrupt key input Allows special keyboard keys to be input; refer to Appendix D Determines whether 7 or 8 bits of keyboard input are read Transforms getch() into a nonblocking call Controls a delay after Esc key press Disables all keyboard buffering and key traps; enters raw mode text processing Flushes input on the SUSP, QUIT, and INTR keys Similar to cbreak (and halfdelay) mode but with a variable timeout value Enables/disables typeahead interrupt on refresh





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The echo()/noecho() functions control whether or not getch() displays its input on the screen. Normally, getch() displays each character typed as its input; no refresh() is required. To turn getch() into a non-blocking call (meaning getch() does not wait for a key to be pressed), use nodelay(). See nodelay(). To read non-alphanumeric keys on the keyboard, the keypad() function is used. See keypad(). Input modification functions that are not window-specific apply to all input for getch(), as well as getstr(). To read a character at a specific location on the screen, the inch() function is used. To insert a character, pushing text to the right, use the insch() function. Remember that getch() returns an int value, not a char. There are still a few old fogies such as myself who will mistakenly use char variables with getch(). Nope! Use int variables.

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transport the material by light, certain stiffness is necessary to prevent any relaxation of the induced relief structure The compromise between these opposite effects has to be found for effective grating formation Thermal treatment is only one of the possible ways to shift this equilibrium As expected, the gratings recorded in ionic materials are thermally very stable After heating the sample to 1001C, they remained stable with ZnormE90%, where Znorm=Zheated/Zrecorded Heating to 1501C erased the grating to ZnormE75%, but even after heating the sample to 2001C, ZnormE40% retained The grating could not be written again onto the thermally treated lm that may be explained by further sol gel condensation, which increases the rigidity of the matrix Thus the latter approach combines a very high ef ciency of SRG formation with a high stability of the induced surface structures provided by the simultaneously formed polymer network.

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