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Already in 1980 (Shinkai et al, 1980), azobenzene moiety had been introduced into crown ether Other recent examples include azobenzene cyclodextrin complexes (Callari et al, 2006), azobenzene-attached nanotube cyclodextrin complexes (Descalzo et al, 2006), and molecular recognition complexes with DNA (Haruta et al, 2008) Numerous examples of photoswitchable azobenzene supramolecular systems in solutions can be found (Yagai et al, 2005; Balzani et al, 2002) But there are no investigations in these systems concerning photoorientation and mass transport There are a large number of publications on photoinduced anisotropy in supramolecular-ordered azobenzene-containing systems, such as liquid crystals (Kreuzer et al, 2000; Szabados et al, 1998), liquid crystalline polymers (Rosenhauer et al, 2001; Han et al, 2000), LbL (Geue et al, 1997; Stumpe et al, 1996), self-assembled monolayers (Sekkat et al, 1995), and adsorbed azobenezene molecules (West et al.



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, 2001) But mass transport resulting in SRG was only reported till recently in glassy systems The considerations here will be limited to azobenzene supramolecular materials for photoorientation and photoinduced mass transport These materials are based on H-bonds and ionic interactions of opposite-charged species Two types of azobenzene-containing supramolecular complexes either with low-molecular-weight surfactants or related macromolecules, which means polyelectrolytes or polymers able to form H-bonding, will be reported that are schematically depicted in Fig 22d The use of such supramolecular building blocks principle would offer new perspectives for the design of functionalized materials In addition, this approach allows to use environment-friendly solvents for material preparation and to considerably decrease the price of the materials by applying of commercially available components as building blocks The photoinduced orientation is reviewed in Section 22.

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Most of the chemical structures of the compounds are also presented in this chapter, and the formation of the corresponding complexes is discussed These complexes include LbL multilayer systems formed by polyelectrolytes and either azobenzenes (or other.

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low-molecular-weight azobenzene derivatives) or main-chain and side-chain azobenzene-containing polyelectrolytes. The results on photoinduced orientation in supramolecular complexes based on either H-bonds or ionic interactions will also be discussed. The ionic complexes are formed by either polyelectrolytes or surfactants and azobenzenes (similar to ones used for LbL process). Complexes between azobenzenes and surfactants formed by ionic self-assembly (ISA) will be concentrated on, as they have shown the best results for photoorientation. Section 2.3 is dedicated to the light-induced formation of relief structures in supramolecular materials. To the best of the authors knowledge, not a lot of results have been published up to date. The authors have tried to include all results in their review, starting with LbL lms and continuing with ionic and H-bond complexes, both amorphous and liquid crystalline ones. Wherever possible, they have commented on different mechanisms of the relief formation in these materials. In particular, they have emphasized the role of the matrix for the light-driven mass transport. They have also tried to combine these very recent results with those well known from the literature on complex formation, materials properties, and light-driven mass transport, if they found it useful for understanding. In summary, the authors derive the advantages and drawbacks of the new supramolecular materials for photoinduced orientation and SRG formation. Also, the questions that were aroused only on the application of the supramolecular systems for orientation and SRG formation are brie y discussed.

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