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The azobenzene chromophore is a unique molecular switch, exhibiting a clean and reversible photoisomerization that induces a reversible change in geometry (Yager and Barrett, 2006a). This motion can be exploited as a photoswitch, and ampli ed so that larger-scale material properties are switched or altered in response to light. Thus, azo materials offer a promising potential as photomechanical materials. In addition to being useful in a variety of photoswitching roles, the azobenzene isomerization, being fundamentally a geometrical motion, can give rise to many types of motion. These motions can lead to formation of structures at a variety of length scales, from molecular to macroscopic. Furthermore, the formation of these structures is optically controlled, which is very attractive to modern industry. At a molecular level, there is much promise in exploiting azobenzenes to control the organization of nanomaterials and the functioning of nanomechanical devices. At a nanometer level, these materials can be used to form arbitrary surface patterns in a single-step process. At a macroscopic level, the motion could be exploited in a variety of photoactuators and arti cial muscles. With regard to the mechanism of surface mass transport, there is a need for further theory and experiments. An emerging possibility is that two competing mechanisms apply at different power levels. In some systems, notably LC ones, motion is suf ciently free that the high power mechanism is readily accessible.





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qiflush()

If more than one INVOCATION INTERCEPTOR is applicable to an invocation, the interceptors are often interdependent. In most cases, therefore, they are arranged in a chain of interceptors. Each INVOCATION INTERCEPTOR forwards the invocation to the next interceptor in the chain. Alternatively, the components that provide the hooks, such as REQUESTOR and INVOKER, can manage the passing of information between elements of the chain. An INVOCATION INTERCEPTOR can use the invocation data to do whatever it wants. The INVOCATION INTERCEPTOR might just read the passed parameters, modify them, or even interrupt further processing and report a REMOTING ERROR to the client. Note that there are distributed object middleware systems that do not permit the modification of all the invocation data.

The qiflush() and noqiflush() function control whether or not the keyboard input buffer is flushed when the Interrupt, Quit, or Suspend keys are used.

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Such an interpretation seems to resolve the apparent con ict between many different results. The nature of the two mechanisms, of course, remains an open question. The high power mechanism may be because of mean- eld forces. Again, in mobile LC systems, or at suf cient power, one might expect molecules to align, attract one another, and move cooperatively. In the low power regime, a photomechanical mechanism appears tenable, although polarization questions need to be addressed, presumably by appealing to photoorientation phenomena. From an applied perspective, the azopolymers are well suited for some types of high performance optical lithography. Speci cally, these materials have been patterned at the subdiffraction limit level, thus showing that any material resolution limits are below the usual optical limits. The double period gratings that have been produced show that these systems are amenable to subdiffraction limit patterning even with far- eld illumination. Ongoing research is evaluating these effects in terms of facile optical formation of nanostructures.

void qiflush(void); void noqiflush(void);

INVOCATION INTERCEPTORS are configured typically via external configuration files or via programming interfaces. External configuration has the advantage that it allows the interceptors to be modified without recompilation. A programmatic interface has the advantage that INVOCATION INTERCEPTORS can be added and removed dynamically at runtime.

The functions take no arguments. The qiflush() function directs NCurses to flush any text waiting in the input queue whenever the Interrupt, Quit, or Suspend keys are pressed. The noqiflush() function directs NCurses to retain whatever text is in the buffer, which is typically flushed out at the next command prompt.

This work is dedicated to professors Almeria Natansohn and Sukant Tripathy, teachers and pioneers in the eld of azopolymers, who were unable to see the completion of this book.

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