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moment for the trans isomer than the cis isomer (Simmons et al, 2007), should not be used because of the opposite change in dipole moment upon UV light illumination Another consideration also does not favor the use of azobenzene derivatives with strong electron-donor and electron-acceptor groups This pattern of substitution on azobenzene usually results in overlap of the absorption of transazobenzene (p-p*) with that of cis-azobenzene (n-p*), in the 440 460 nm region Not only does the cis isomer have a fast thermally activated relaxation back to the trans isomer, photons absorbed by trans-azobenzene, inducing the trans cis isomerization, can also be signi cantly absorbed by cis-azobenzene that induces the reverse cis trans isomerization The consequence of the fast thermal relaxation of cisazobenzene and the simultaneous photoisomerization in the two directions is that few azobenzene moieties in the cis form can stay.



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/* Fill most of the screen with random 6-char words */ for(x=0;x<200;x++) { for(w=0;w<6;w++) word[w] = (random() % 26) + a ; printw( %s\t ,word); } addch( \n ); addstr( Press Enter to write this screen to disk\n ); refresh(); getch(); /* write the window to disk */ r = scr_dump(FILENAME); if( r == ERR) addstr( Error writing window to disk\n ); else addstr( File written; press Enter to quit\n ); refresh(); getch(); endwin(); return 0; }

opt [token is not ok]

The sample output is shown in Figure A-12.





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Obviously, for light-controllable polymer micelles, a bistable photoswitch is preferred As far as azobenzene is concerned, its derivatives that can undergo a thorough trans cis isomerization upon UV light illumination and have thermally stable cis isomer are mostly interesting From the above analysis, using azobenzene BCPs, a signi cant increase in dipole moment accompanying the trans cis isomerization of the chromophore under UV light can increase the entire polarity of the hydrophobic polymer block and, consequently, shift the hydrophilic hydrophobic balance in the direction thermodynamically unfavorable to the micellar association Although the micellar association is very sensitive to the balance, such a shift may not be necessarily enough to cause the dissociation of BCP micelles; other factors need to be taken into consideration This can be illustrated using a classical small-molecule surfactant as example.

14, scr_restore(), putwin()

scr_init()

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Session handling is another interesting feature that can be implemented easily using the patterns introduced in this chapter. As explained more deeply in 13, Related Concepts, Technologies, and Patterns, sessions can be used to provide state to otherwise stateless remote objects. Using a client-specific session object, instead of making all the remote objects stateful, CLIENT-DEPENDENT INSTANCES makes scalability, failover, and load-balancing easier to achieve in most cases. The example in the next diagram uses non-persistent sessions. These are only stored in memory by the SessionRegistry. If persistent sessions must be supported, the respective INVOCATION INTERCEPTOR would have to make sure the session data is loaded in beforeInvocation and also save potential changes in afterInvocation. In the example below, beforeInvocation handles the session using the session registry and afterInvocation does nothing. The sequence diagram shows two session-handling scenarios: The session does not yet exist. A session object is created, added to the session registry, then used for the invocation.

The anionic surfactants of CH3(CH2)nNHCOO has a cmc sensitive to the hydrophilic hydrophobic balance; the cmc is 18 10 4 mol dm 3 for n=13, while it is reduced by an order to 18 10 5 mol dm 3 for n=15 (longer hydrocarbon tail) (Everett DH, 1988) Now, imagine a micellar solution of the surfactant with n=15 exposed to light, if somehow two methylene groups were removed from the hydrocarbon tail, the micelles would be dissociated if the surfactant concentration in solution was below 18 10 4 mol dm 3 (cmc of the surfactant with n=13), while they would remain if the surfactant concentration was above this cmc This simple example points to the fact that an important shift in the hydrophilic hydrophobic balance alone may not be enough to result in the dissociation of the micelles and that other conditions need to be ful lled.

The scr_init() function reads the window data saved to disk by scr_dump() and uses information from that file to configure the screen.

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